X-ray studies of the electrolyte distribution at the interface between two polar liquids

Mark L. Schlossman; Guangming Luo; Sarka Malkova; Sai V. Pingali; David Schultz; Binhua Lin; Mati Meron; Petr Vanysek

X-ray studies of the electrolyte distribution at the interface between two polar liquids

Mark L. Schlossman, Guangming Luo, Sarka Malkova, Sai V. Pingali, David Schultz, Binhua Lin, Mati Meron, Petr Vanysek

Research output: Contribution to journal › Conference article › peer-review

Abstract

X-ray reflectivity is used to probe the interface between two polar liquids (nitrobenzene and water). Addition of the electrolytes TBABr to the water and TBATPB to the nitrobenzene induces an electrostatic potential across the interface. For larger potential (fixed by the electrolyte concentration), the electrolyte distribution differs from the GouyChapman prediction. Deviations from the Gouy-Chapman theory are also measured in studies of the interlace between an aqueous solution of BaCl₂ and a nitrobenzene solution of TBATPB. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

Original language	English
Journal	ACS National Meeting Book of Abstracts
Volume	230
State	Published - 2005
Externally published	Yes
Event	230th ACS National Meeting - Washington, DC, United States Duration: Aug 28 2005 → Sep 1 2005

Cite this

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title = "X-ray studies of the electrolyte distribution at the interface between two polar liquids",

abstract = "X-ray reflectivity is used to probe the interface between two polar liquids (nitrobenzene and water). Addition of the electrolytes TBABr to the water and TBATPB to the nitrobenzene induces an electrostatic potential across the interface. For larger potential (fixed by the electrolyte concentration), the electrolyte distribution differs from the GouyChapman prediction. Deviations from the Gouy-Chapman theory are also measured in studies of the interlace between an aqueous solution of BaCl2 and a nitrobenzene solution of TBATPB. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).",

author = "Schlossman, {Mark L.} and Guangming Luo and Sarka Malkova and Pingali, {Sai V.} and David Schultz and Binhua Lin and Mati Meron and Petr Vanysek",

year = "2005",

language = "English",

volume = "230",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

note = "230th ACS National Meeting ; Conference date: 28-08-2005 Through 01-09-2005",

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TY - JOUR

T1 - X-ray studies of the electrolyte distribution at the interface between two polar liquids

AU - Schlossman, Mark L.

AU - Luo, Guangming

AU - Malkova, Sarka

AU - Pingali, Sai V.

AU - Schultz, David

AU - Lin, Binhua

AU - Meron, Mati

AU - Vanysek, Petr

PY - 2005

Y1 - 2005

N2 - X-ray reflectivity is used to probe the interface between two polar liquids (nitrobenzene and water). Addition of the electrolytes TBABr to the water and TBATPB to the nitrobenzene induces an electrostatic potential across the interface. For larger potential (fixed by the electrolyte concentration), the electrolyte distribution differs from the GouyChapman prediction. Deviations from the Gouy-Chapman theory are also measured in studies of the interlace between an aqueous solution of BaCl2 and a nitrobenzene solution of TBATPB. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

AB - X-ray reflectivity is used to probe the interface between two polar liquids (nitrobenzene and water). Addition of the electrolytes TBABr to the water and TBATPB to the nitrobenzene induces an electrostatic potential across the interface. For larger potential (fixed by the electrolyte concentration), the electrolyte distribution differs from the GouyChapman prediction. Deviations from the Gouy-Chapman theory are also measured in studies of the interlace between an aqueous solution of BaCl2 and a nitrobenzene solution of TBATPB. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

UR - http://www.scopus.com/inward/record.url?scp=33745333275&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:33745333275

SN - 0065-7727

VL - 230

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

T2 - 230th ACS National Meeting

Y2 - 28 August 2005 through 1 September 2005

ER -

X-ray studies of the electrolyte distribution at the interface between two polar liquids

Abstract

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