X-ray irradiation induces local rearrangement of silica particles in swollen rubber

Yuya Shinohara; Naoko Yamamoto; Hiroyuki Kishimoto; Yoshiyuki Amemiya

doi:10.1107/S1600577514022954

X-ray irradiation induces local rearrangement of silica particles in swollen rubber

Yuya Shinohara
, Naoko Yamamoto
, Hiroyuki Kishimoto
, Yoshiyuki Amemiya

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

X-ray photon correlation spectroscopy (XPCS) of swollen rubber containing spherical silica nanoparticles is reported. It is shown that irradiation by intense X-rays leads to the breakdown of cross-links, thereby inducing the local rearrangement of silica nanoparticles. This rearrangement process depends on the cross-link density and is characterized by a compressed exponential relaxation with aging behaviour, which resembles a common feature of complex fluids observed with XPCS.

Original language	English
Pages (from-to)	119-123
Number of pages	5
Journal	Journal of Synchrotron Radiation
Volume	22
Issue number	1
DOIs	https://doi.org/10.1107/S1600577514022954
State	Published - Jan 1 2015
Externally published	Yes

Keywords

X-ray photon correlation spectroscopy
filled rubber

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10.1107/S1600577514022954

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title = "X-ray irradiation induces local rearrangement of silica particles in swollen rubber",

abstract = "X-ray photon correlation spectroscopy (XPCS) of swollen rubber containing spherical silica nanoparticles is reported. It is shown that irradiation by intense X-rays leads to the breakdown of cross-links, thereby inducing the local rearrangement of silica nanoparticles. This rearrangement process depends on the cross-link density and is characterized by a compressed exponential relaxation with aging behaviour, which resembles a common feature of complex fluids observed with XPCS.",

keywords = "X-ray photon correlation spectroscopy, filled rubber",

author = "Yuya Shinohara and Naoko Yamamoto and Hiroyuki Kishimoto and Yoshiyuki Amemiya",

note = "Publisher Copyright: {\textcopyright} 2015 International Union of Crystallography.",

year = "2015",

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doi = "10.1107/S1600577514022954",

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T1 - X-ray irradiation induces local rearrangement of silica particles in swollen rubber

AU - Shinohara, Yuya

AU - Yamamoto, Naoko

AU - Kishimoto, Hiroyuki

AU - Amemiya, Yoshiyuki

PY - 2015/1/1

Y1 - 2015/1/1

N2 - X-ray photon correlation spectroscopy (XPCS) of swollen rubber containing spherical silica nanoparticles is reported. It is shown that irradiation by intense X-rays leads to the breakdown of cross-links, thereby inducing the local rearrangement of silica nanoparticles. This rearrangement process depends on the cross-link density and is characterized by a compressed exponential relaxation with aging behaviour, which resembles a common feature of complex fluids observed with XPCS.

AB - X-ray photon correlation spectroscopy (XPCS) of swollen rubber containing spherical silica nanoparticles is reported. It is shown that irradiation by intense X-rays leads to the breakdown of cross-links, thereby inducing the local rearrangement of silica nanoparticles. This rearrangement process depends on the cross-link density and is characterized by a compressed exponential relaxation with aging behaviour, which resembles a common feature of complex fluids observed with XPCS.

KW - X-ray photon correlation spectroscopy

KW - filled rubber

UR - https://www.scopus.com/pages/publications/84920031156

U2 - 10.1107/S1600577514022954

DO - 10.1107/S1600577514022954

M3 - Article

AN - SCOPUS:84920031156

SN - 0909-0495

VL - 22

SP - 119

EP - 123

JO - Journal of Synchrotron Radiation

JF - Journal of Synchrotron Radiation

IS - 1

ER -

X-ray irradiation induces local rearrangement of silica particles in swollen rubber

Abstract

Keywords

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