When does a crystal conduct heat like a glass?

B. C. Sales, B. C. Chakoumakos, V. Keppens, R. Jin, D. Mandrus, J. R. Thompson

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Semiconducting crystalline materials that are poor conductors of heat are important as thermoelectric materials and for technological applications involving thermal management. In the present article neutron scattering, electrical and thermal transport, heat capacity, magnetic and acoustic measurements are reported on single crystals of three semiconductors with the type I clathrate structure: Ba8Ga16Ge30, Sr8Ga16Ge30 and Eu8Ga16Ge30. Taken together these measurements suggest specific structural features that result in a crystal with the lowest possible thermal conductivity, namely that of a glass with the same chemical composition. Weakly bound atoms that rattle within oversized atomic cages in a crystal result in a low thermal conductivity, but the present data show that both rattling atoms and tunneling states are necessary to produce a true glass-like thermal conductivity.

Original languageEnglish
Pages (from-to)161-168
Number of pages8
JournalMaterials Research Society Symposium - Proceedings
Volume691
StatePublished - 2002
Externally publishedYes

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