Abstract
In spite of the recent advances in the development of high performing piezoelectric materials, their applications are typically limited to the direct conversion of mechanical impact energy to electrical energy, potentially risking mechanical failures. In this study, we developed piezoelectric poly(vinylidenefluoride-trifluoroethylene) (P(VDF-TrFE)) nanofibers integrated with SiO2-shelled Fe3O4 magnetic nanoparticles, to utilize magnetic energy to reliably drive the piezoelectric effect. Specifically, we show that the shape of the magnetic nanoparticles exerts a significant effect on the efficiency of the magneto-mechano-electrical energy conversion as magnetic nanorods exhibit approximately 70% enhancement in electric field generation under cyclic magnetic fields as compared to nanospheres. Under an alternating magnetic field of 200 mT, the magnetic nanorod-piezoelectric nanofiber composite generated a peak-to-peak voltage of approximately 30 mVp-p with a superior durability without any performance degradation after over 1 million cycles. This study demonstrates the potential of magnetic-field responsive, piezoelectric-based materials in energy harvesting applications from non-mechanical energy sources.
Original language | English |
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Pages (from-to) | 20527-20533 |
Number of pages | 7 |
Journal | Nanoscale |
Volume | 11 |
Issue number | 43 |
DOIs | |
State | Published - Nov 21 2019 |
Externally published | Yes |
Funding
This work was supported by the Creative Materials Discovery Program through the National Research Foundation of Korea funded by the Ministry of Science and ICT (2018M3D1A1057844), and the UC Riverside and the Korea Institute of Materials Science (Research Program POC2930) through the UC-KIMS Center for Innovative Materials for Energy and Environment.
Funders | Funder number |
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Creative Materials Discovery Program | |
UC-KIMS Center for Innovative Materials for Energy and Environment | |
University of California, Riverside | |
Ministry of Science, ICT and Future Planning | |
Korea Institute of Materials Science | POC2930 |
National Research Foundation of Korea | |
Ministry of Science ICT and Future Planning | 2018M3D1A1057844 |