Abstract
Uranium extraction from seawater (UES), a potential approach to securing the long-term uranium supply and sustainability of nuclear energy, has experienced significant progress in the past decade. Promising adsorbents with record-high capacities have been developed by diverse innovative synthetic strategies, and scale-up marine field tests have been put forward by several countries. However, significant challenges remain in terms of the adsorbents’ properties in complex marine environments, deployment methods, and the economic viability of current UES systems. This review presents an up-to-date overview of the latest advancements in the UES field, highlighting new insights into the mechanistic basis of UES and the methodologies towards the function-oriented development of uranium adsorbents with high adsorption capacity, selectivity, biofouling resistance, and durability. A distinctive emphasis is placed on emerging electrochemical and photochemical strategies that have been employed to develop efficient UES systems. The most recent achievements in marine tests by the major countries are summarized. Challenges and perspectives related to the fundamental, technical, and engineering aspects of UES are discussed. This review is envisaged to inspire innovative ideas and bring technical solutions towards the development of technically and economically viable UES systems.
Original language | English |
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Pages (from-to) | 97-162 |
Number of pages | 66 |
Journal | Chemical Society Reviews |
Volume | 52 |
Issue number | 1 |
DOIs | |
State | Published - Nov 30 2022 |
Externally published | Yes |
Funding
The authors wish to acknowledge the financial support provided by the National Natural Science Fund for Excellent Young Scholars (No. 21922604, G. Ye), the National Natural Science Foundation of China (No. 22206104, Y. Y. Geng), the Robert A. Welch Foundation (B-0027 to S. Q. Ma), the China National Postdoctoral Program for Innovative Talents (No. BX2021142, H. Li) and the Shuimu Tsinghua Scholar Program (No. 2020SM139, H. Li).