TY - JOUR
T1 - Unraveling structural, electronic, and magnetic ambiguities in P b1-δCr O3 with an insulating charge-transfer band structure
AU - Chen, Jian
AU - Song, Guozhu
AU - Ge, Han
AU - Dos Santos, Antonio M.
AU - Wu, Liusuo
AU - Zhao, Yusheng
AU - Wang, Shanmin
N1 - Publisher Copyright:
© 2025 American Physical Society.
PY - 2025/1/15
Y1 - 2025/1/15
N2 - As a recently identified Mott system, PbCrO3 remains largely unexplored, especially for its band structure, leading to many contentious issues on its structural, electronic, and magnetic properties. Here we present a comprehensive study of two different Pb1-δCrO3 (δ= 0 and 0.15) samples involving atomic deficiency prepared under pressure. By means of state-of-the-art diffraction techniques, the crystal structure of PbCrO3 is definitively determined to adopt the pristine Pm3¯m symmetry, rather than other previously misassigned structures of M2-Pm3¯m and Pmnm. The two materials exhibit a similar charge-transfer-type insulating band structure, and the charge-transfer effect splits both Cr 2p and Pb 4f orbitals, rationalizing doublet splitting of the associated spectral lines. Nearly identical nominal cationic valence states of Cr4+ and Pb2+ are identified for this oxide system, hence calling into question the validity of recently proposed charge disproportionation mechanisms. In addition, Pb0.85CrO3 exhibits an anomalously higher Néel temperature of ∼240 K than that of PbCrO3 (i.e., ∼200 K), likely due to the deficiency-induced enhancements of Cr3d-O2p orbital overlap and magnetic exchange. These findings provide much solid evidence to look into the fundamental properties of this important material system.
AB - As a recently identified Mott system, PbCrO3 remains largely unexplored, especially for its band structure, leading to many contentious issues on its structural, electronic, and magnetic properties. Here we present a comprehensive study of two different Pb1-δCrO3 (δ= 0 and 0.15) samples involving atomic deficiency prepared under pressure. By means of state-of-the-art diffraction techniques, the crystal structure of PbCrO3 is definitively determined to adopt the pristine Pm3¯m symmetry, rather than other previously misassigned structures of M2-Pm3¯m and Pmnm. The two materials exhibit a similar charge-transfer-type insulating band structure, and the charge-transfer effect splits both Cr 2p and Pb 4f orbitals, rationalizing doublet splitting of the associated spectral lines. Nearly identical nominal cationic valence states of Cr4+ and Pb2+ are identified for this oxide system, hence calling into question the validity of recently proposed charge disproportionation mechanisms. In addition, Pb0.85CrO3 exhibits an anomalously higher Néel temperature of ∼240 K than that of PbCrO3 (i.e., ∼200 K), likely due to the deficiency-induced enhancements of Cr3d-O2p orbital overlap and magnetic exchange. These findings provide much solid evidence to look into the fundamental properties of this important material system.
UR - http://www.scopus.com/inward/record.url?scp=85216424922&partnerID=8YFLogxK
U2 - 10.1103/PhysRevB.111.045143
DO - 10.1103/PhysRevB.111.045143
M3 - Article
AN - SCOPUS:85216424922
SN - 2469-9950
VL - 111
JO - Physical Review B
JF - Physical Review B
IS - 4
M1 - 045143
ER -