Unit-cell-level assembly of metastable transition-metal oxides by pulsed-laser deposition

  • Lei Yan
  • , Hongjun Niu
  • , Craig A. Bridges
  • , Paul A. Marshall
  • , Joke Hadermann
  • , Gustaav Van Tendeloo
  • , Paul R. Chalker
  • , Matthew J. Rosseinsky

Research output: Contribution to journalArticlepeer-review

20 Scopus citations

Abstract

One layer at a time: The sequential pulsed-laser deposition of CaO rock-salt and CaMnO3 perovskite layers on an SrTiO3 substrate allows the growth of the metastable n = 4, 5, and 6 members of the Can+1MnnO3n+1 Ruddlesden-Popper series (see high-resolution TEM image of Ca5Mn4O13). The growth process is monitored using reflection high-energy electron diffraction.

Original languageEnglish
Pages (from-to)4539-4542
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number24
DOIs
StatePublished - 2007
Externally publishedYes

Keywords

  • Electron microscopy
  • Oxides
  • Pulsed-laser deposition
  • Ruddlesden-Popper phases
  • Thin films

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