Uniform Permutation of Quasi-2D Perovskites by Vacuum Poling for Efficient, High-Fill-Factor Solar Cells

Jia Zhang; Jiajun Qin; Miaosheng Wang; Yujie Bai; Han Zou; Jong Kahk Keum; Runming Tao; Hengxing Xu; Haomiao Yu; Stefan Haacke; Bin Hu

doi:10.1016/j.joule.2019.09.020

Uniform Permutation of Quasi-2D Perovskites by Vacuum Poling for Efficient, High-Fill-Factor Solar Cells

Jia Zhang, Jiajun Qin, Miaosheng Wang, Yujie Bai, Han Zou, Jong Kahk Keum, Runming Tao, Hengxing Xu, Haomiao Yu, Stefan Haacke, Bin Hu

Functional Hybrid Nanomaterials

Research output: Contribution to journal › Article › peer-review

195 Scopus citations

Abstract

It is widely accepted that vertically aligning quasi-2D perovskites can improve power conversion efficiency due to directional charge transport from small to large-n-value nanoplates. Here, we report a different strategy of uniformly arranging different-n-value 2D nanoplates (PEA₂MA_n-1Pb_nI_3n+1) based on our vacuum poling method to enable superior isotropic carrier transport. Consequently, the high efficiency of 18.04% with open-circuit voltage of 1.223 V and champion fill-factor (FF) of 82.4% are demonstrated, presenting a new approach to develop advanced quasi-2D perovskite optoelectronic devices.

Original language	English
Pages (from-to)	3061-3071
Number of pages	11
Journal	Joule
Volume	3
Issue number	12
DOIs	https://doi.org/10.1016/j.joule.2019.09.020
State	Published - Dec 18 2019

Funding

The authors at the University of Tennessee acknowledge funding support from the Air Force Office of Scientific Research (AFOSR) under the grant number FA 9550-15-1-0064 , AOARD ( FA2386-15-1-4104 ), and National Science Foundation ( NSF-1911659 ). This research was partially performed at the Center for Nanophase Materials Sciences based on user projects ( CNMS2017-102 ), which is sponsored by Oak Ridge National Laboratory by the Division of Scientific User Facilities, U.S. Department of Energy .

Keywords

2D nanoplates
carrier extraction
high efficiency
high fill factor
perovskite solar cells
quasi-2D perovskites
uniform dispersion
vacuum poling treatment

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.joule.2019.09.020

Cite this

@article{5b651be22ac04043aa96e4482769dcae,

title = "Uniform Permutation of Quasi-2D Perovskites by Vacuum Poling for Efficient, High-Fill-Factor Solar Cells",

abstract = "It is widely accepted that vertically aligning quasi-2D perovskites can improve power conversion efficiency due to directional charge transport from small to large-n-value nanoplates. Here, we report a different strategy of uniformly arranging different-n-value 2D nanoplates (PEA2MAn-1PbnI3n+1) based on our vacuum poling method to enable superior isotropic carrier transport. Consequently, the high efficiency of 18.04% with open-circuit voltage of 1.223 V and champion fill-factor (FF) of 82.4% are demonstrated, presenting a new approach to develop advanced quasi-2D perovskite optoelectronic devices.",

keywords = "2D nanoplates, carrier extraction, high efficiency, high fill factor, perovskite solar cells, quasi-2D perovskites, uniform dispersion, vacuum poling treatment",

author = "Jia Zhang and Jiajun Qin and Miaosheng Wang and Yujie Bai and Han Zou and Keum, {Jong Kahk} and Runming Tao and Hengxing Xu and Haomiao Yu and Stefan Haacke and Bin Hu",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Inc.",

year = "2019",

month = dec,

day = "18",

doi = "10.1016/j.joule.2019.09.020",

language = "English",

volume = "3",

pages = "3061--3071",

journal = "Joule",

issn = "2542-4351",

publisher = "Elsevier",

number = "12",

}

TY - JOUR

T1 - Uniform Permutation of Quasi-2D Perovskites by Vacuum Poling for Efficient, High-Fill-Factor Solar Cells

AU - Zhang, Jia

AU - Qin, Jiajun

AU - Wang, Miaosheng

AU - Bai, Yujie

AU - Zou, Han

AU - Keum, Jong Kahk

AU - Tao, Runming

AU - Xu, Hengxing

AU - Yu, Haomiao

AU - Haacke, Stefan

AU - Hu, Bin

PY - 2019/12/18

Y1 - 2019/12/18

N2 - It is widely accepted that vertically aligning quasi-2D perovskites can improve power conversion efficiency due to directional charge transport from small to large-n-value nanoplates. Here, we report a different strategy of uniformly arranging different-n-value 2D nanoplates (PEA2MAn-1PbnI3n+1) based on our vacuum poling method to enable superior isotropic carrier transport. Consequently, the high efficiency of 18.04% with open-circuit voltage of 1.223 V and champion fill-factor (FF) of 82.4% are demonstrated, presenting a new approach to develop advanced quasi-2D perovskite optoelectronic devices.

AB - It is widely accepted that vertically aligning quasi-2D perovskites can improve power conversion efficiency due to directional charge transport from small to large-n-value nanoplates. Here, we report a different strategy of uniformly arranging different-n-value 2D nanoplates (PEA2MAn-1PbnI3n+1) based on our vacuum poling method to enable superior isotropic carrier transport. Consequently, the high efficiency of 18.04% with open-circuit voltage of 1.223 V and champion fill-factor (FF) of 82.4% are demonstrated, presenting a new approach to develop advanced quasi-2D perovskite optoelectronic devices.

KW - 2D nanoplates

KW - carrier extraction

KW - high efficiency

KW - high fill factor

KW - perovskite solar cells

KW - quasi-2D perovskites

KW - uniform dispersion

KW - vacuum poling treatment

UR - http://www.scopus.com/inward/record.url?scp=85076253623&partnerID=8YFLogxK

U2 - 10.1016/j.joule.2019.09.020

DO - 10.1016/j.joule.2019.09.020

M3 - Article

AN - SCOPUS:85076253623

SN - 2542-4351

VL - 3

SP - 3061

EP - 3071

JO - Joule

JF - Joule

IS - 12

ER -

Uniform Permutation of Quasi-2D Perovskites by Vacuum Poling for Efficient, High-Fill-Factor Solar Cells

Abstract

Funding

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this