Two-dimensional S = 1 quantum antiferromagnet (NiCl)Sr2Ta 3O10

Yoshihiro Tsujimoto; Atsushi Kitada; Yasutomo J. Uemura; Tatsuo Goko; Adam A. Aczel; Travis J. Williams; Graeme M. Luke; Yasuo Narumi; Koichi Kindo; Masakazu Nishi; Yoshitami Ajiro; Kazuyoshi Yoshimura; Hiroshi Kageyama

doi:10.1021/cm100660v

Two-dimensional S = 1 quantum antiferromagnet (NiCl)Sr₂Ta ₃O₁₀

Yoshihiro Tsujimoto
, Atsushi Kitada
, Yasutomo J. Uemura
, Tatsuo Goko
, Adam A. Aczel
, Travis J. Williams
, Graeme M. Luke
, Yasuo Narumi
, Koichi Kindo
, Masakazu Nishi
, Yoshitami Ajiro
, Kazuyoshi Yoshimura
, Hiroshi Kageyama

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A topotactic ion-exchange reaction of a layered perovskite RbSr ₂Ta₃O₁₀ with NiCl₂ yielded a novel two-dimensional nickel-oxyhalide (NiCl)Sr₂Ta₃O ₁₀, the first S = 1 compound among related series of metal-oxyhalides. The room temperature structure is isostructural with (CuCl)Ca₂Nb₃O₁₀ adopting the space group P4/mmm. We found a possible structural transition at 230 K that does not lead to drastic changes in magnetic character such as nickel clustering. Despite a large Weiss temperature of θ =-125 K, magnetic long-range order is significantly suppressed down to T_N1 ≈ 50 K because of two-dimensionality and strong frustration. The magnetically ordered state below T_N1 has a partial volume fraction coexisting with a paramagnetic component, followed by complete long-range ordering below T_N2 = 20 K. The reaction process and requirement will also be discussed.

Original language	English
Pages (from-to)	4625-4631
Number of pages	7
Journal	Chemistry of Materials
Volume	22
Issue number	16
DOIs	https://doi.org/10.1021/cm100660v
State	Published - Aug 24 2010
Externally published	Yes

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@article{796f1e685eb443e2bc601843aa4e74f6,

title = "Two-dimensional S = 1 quantum antiferromagnet (NiCl)Sr2Ta 3O10",

abstract = "A topotactic ion-exchange reaction of a layered perovskite RbSr 2Ta3O10 with NiCl2 yielded a novel two-dimensional nickel-oxyhalide (NiCl)Sr2Ta3O 10, the first S = 1 compound among related series of metal-oxyhalides. The room temperature structure is isostructural with (CuCl)Ca2Nb3O10 adopting the space group P4/mmm. We found a possible structural transition at 230 K that does not lead to drastic changes in magnetic character such as nickel clustering. Despite a large Weiss temperature of θ =-125 K, magnetic long-range order is significantly suppressed down to TN1 ≈ 50 K because of two-dimensionality and strong frustration. The magnetically ordered state below TN1 has a partial volume fraction coexisting with a paramagnetic component, followed by complete long-range ordering below TN2 = 20 K. The reaction process and requirement will also be discussed.",

author = "Yoshihiro Tsujimoto and Atsushi Kitada and Uemura, \{Yasutomo J.\} and Tatsuo Goko and Aczel, \{Adam A.\} and Williams, \{Travis J.\} and Luke, \{Graeme M.\} and Yasuo Narumi and Koichi Kindo and Masakazu Nishi and Yoshitami Ajiro and Kazuyoshi Yoshimura and Hiroshi Kageyama",

year = "2010",

month = aug,

day = "24",

doi = "10.1021/cm100660v",

language = "English",

volume = "22",

pages = "4625--4631",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "16",

}

TY - JOUR

T1 - Two-dimensional S = 1 quantum antiferromagnet (NiCl)Sr2Ta 3O10

AU - Tsujimoto, Yoshihiro

AU - Kitada, Atsushi

AU - Uemura, Yasutomo J.

AU - Goko, Tatsuo

AU - Aczel, Adam A.

AU - Williams, Travis J.

AU - Luke, Graeme M.

AU - Narumi, Yasuo

AU - Kindo, Koichi

AU - Nishi, Masakazu

AU - Ajiro, Yoshitami

AU - Yoshimura, Kazuyoshi

AU - Kageyama, Hiroshi

PY - 2010/8/24

Y1 - 2010/8/24

N2 - A topotactic ion-exchange reaction of a layered perovskite RbSr 2Ta3O10 with NiCl2 yielded a novel two-dimensional nickel-oxyhalide (NiCl)Sr2Ta3O 10, the first S = 1 compound among related series of metal-oxyhalides. The room temperature structure is isostructural with (CuCl)Ca2Nb3O10 adopting the space group P4/mmm. We found a possible structural transition at 230 K that does not lead to drastic changes in magnetic character such as nickel clustering. Despite a large Weiss temperature of θ =-125 K, magnetic long-range order is significantly suppressed down to TN1 ≈ 50 K because of two-dimensionality and strong frustration. The magnetically ordered state below TN1 has a partial volume fraction coexisting with a paramagnetic component, followed by complete long-range ordering below TN2 = 20 K. The reaction process and requirement will also be discussed.

AB - A topotactic ion-exchange reaction of a layered perovskite RbSr 2Ta3O10 with NiCl2 yielded a novel two-dimensional nickel-oxyhalide (NiCl)Sr2Ta3O 10, the first S = 1 compound among related series of metal-oxyhalides. The room temperature structure is isostructural with (CuCl)Ca2Nb3O10 adopting the space group P4/mmm. We found a possible structural transition at 230 K that does not lead to drastic changes in magnetic character such as nickel clustering. Despite a large Weiss temperature of θ =-125 K, magnetic long-range order is significantly suppressed down to TN1 ≈ 50 K because of two-dimensionality and strong frustration. The magnetically ordered state below TN1 has a partial volume fraction coexisting with a paramagnetic component, followed by complete long-range ordering below TN2 = 20 K. The reaction process and requirement will also be discussed.

UR - https://www.scopus.com/pages/publications/77955678794

U2 - 10.1021/cm100660v

DO - 10.1021/cm100660v

M3 - Article

AN - SCOPUS:77955678794

SN - 0897-4756

VL - 22

SP - 4625

EP - 4631

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 16

ER -

Two-dimensional S = 1 quantum antiferromagnet (NiCl)Sr₂Ta ₃O₁₀

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