@article{9052d5e61de44ac6965c1d350d96200f,
title = "Tris(thiocyanato-κN)tris(triphenylphosphine oxide-κO) terbium(III)",
abstract = "The title compound, [Tb(NCS)3(C18H15OP)3], contains a six-coordinate TbII cation surrounded by three O-bound triphenylphosphine oxide ligands and three N-bound thiocyanate ligands, each in a fac arrangement. There are two crystallographically unique TbIII atoms in the asymmetric unit. One TbIII atom resides on a threefold rotation axis, while the other has no imposed crystallographic symmetry. The thiocyanate ligands are bound through N atoms, illustrating the hard-hard bonding principles of metal complex chemistry.",
keywords = "R factor = 0.026, T = 180 K, data-to-parameter ratio = 15.5, mean ω(C-C) = 0.006 {\AA}, single-crystal X-ray study, wR factor = 0.056",
author = "Pham, {Lam N.} and Thames, {Anthony T.} and White, {Frankie D.} and Xiang, {Kang Rui} and Sykora, {Richard E.}",
year = "2012",
month = dec,
doi = "10.1107/S1600536812047289",
language = "English",
volume = "68",
pages = "m1531",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
number = "12",
}