Tris(tetrabutylammonium)is(nitrato-K2O,O′)tetra-kis- (thiocyanatoK-N)thorium(IV)

M. Janeth Lozano-Rodriguez; Pierre Thuéry; Sébastien Petit; Roy Copping; Jose Mustre De Leon; Christophe Den Auwer

doi:10.1107/S1600536811009792

Tris(tetrabutylammonium)is(nitrato-K²O,O′)tetra-kis- (thiocyanatoK-N)thorium(IV)

M. Janeth Lozano-Rodriguez, Pierre Thuéry, Sébastien Petit, Roy Copping, Jose Mustre De Leon, Christophe Den Auwer

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The title compound, (C₁₆H₃₆N)₃[Th(NCS) ₄(NO₃)₃], was obtained from the reaction of Th(NO₃)₄·5H₂O with (Bu ₄N)(NCS). The Th^IV atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thio-cyanate ions and to three bidentate nitrate ions. The average Th - N and Th - O bond lengths are 2.481 (10) and 2.57 (3) Å, respectively.

Original language	English
Pages (from-to)	m487
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	4
DOIs	https://doi.org/10.1107/S1600536811009792
State	Published - Apr 2011
Externally published	Yes

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title = "Tris(tetrabutylammonium)is(nitrato-K2O,O′)tetra-kis- (thiocyanatoK-N)thorium(IV)",

abstract = "The title compound, (C16H36N)3[Th(NCS) 4(NO3)3], was obtained from the reaction of Th(NO3)4·5H2O with (Bu 4N)(NCS). The ThIV atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thio-cyanate ions and to three bidentate nitrate ions. The average Th - N and Th - O bond lengths are 2.481 (10) and 2.57 (3) {\AA}, respectively.",

author = "Lozano-Rodriguez, {M. Janeth} and Pierre Thu{\'e}ry and S{\'e}bastien Petit and Roy Copping and {Mustre De Leon}, Jose and {Den Auwer}, Christophe",

year = "2011",

month = apr,

doi = "10.1107/S1600536811009792",

language = "English",

volume = "67",

pages = "m487",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

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TY - JOUR

T1 - Tris(tetrabutylammonium)is(nitrato-K2O,O′)tetra-kis- (thiocyanatoK-N)thorium(IV)

AU - Lozano-Rodriguez, M. Janeth

AU - Thuéry, Pierre

AU - Petit, Sébastien

AU - Copping, Roy

AU - Mustre De Leon, Jose

AU - Den Auwer, Christophe

PY - 2011/4

Y1 - 2011/4

N2 - The title compound, (C16H36N)3[Th(NCS) 4(NO3)3], was obtained from the reaction of Th(NO3)4·5H2O with (Bu 4N)(NCS). The ThIV atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thio-cyanate ions and to three bidentate nitrate ions. The average Th - N and Th - O bond lengths are 2.481 (10) and 2.57 (3) Å, respectively.

AB - The title compound, (C16H36N)3[Th(NCS) 4(NO3)3], was obtained from the reaction of Th(NO3)4·5H2O with (Bu 4N)(NCS). The ThIV atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thio-cyanate ions and to three bidentate nitrate ions. The average Th - N and Th - O bond lengths are 2.481 (10) and 2.57 (3) Å, respectively.

UR - http://www.scopus.com/inward/record.url?scp=79953786287&partnerID=8YFLogxK

U2 - 10.1107/S1600536811009792

DO - 10.1107/S1600536811009792

M3 - Article

AN - SCOPUS:79953786287

SN - 1600-5368

VL - 67

SP - m487

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Tris(tetrabutylammonium)is(nitrato-K²O,O′)tetra-kis- (thiocyanatoK-N)thorium(IV)

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