Trinuclear complexes of copper, cobalt and iron with N,N′-di(2-pyridyl)formamidinate ligands, [M3(DPyF)4][PF6]2

F. Albert Cotton; Carlos A. Murillo; Xiaoping Wang

doi:10.1016/S1387-7003(98)00063-X

Trinuclear complexes of copper, cobalt and iron with N,N′-di(2-pyridyl)formamidinate ligands, [M₃(DPyF)₄][PF₆]₂

F. Albert Cotton, Carlos A. Murillo, Xiaoping Wang

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Three isomorphous linear trinuclear complexes [M₃(DPyF)₄] [PF₆]₂·4CH₃CN·2Et₂O, M=Cu(II), Co(II), Fe(II), DPyF=N,N′-di(2-pyridyl) formamidinate, have been synthesized and their structures have been determined by single crystal X-ray crystallography. The structure of the cations in these compounds consists of a linear, symmetrical chain of metal atoms. The central metal atom is coordinated by four nitrogen atoms that form a ruffled planar array while the outer atoms are six-coordinate.

Original language	English
Pages (from-to)	281-283
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	1
Issue number	8
DOIs	https://doi.org/10.1016/S1387-7003(98)00063-X
State	Published - Aug 1998
Externally published	Yes

Funding

We thank the National Science Foundation for support.

Keywords

Cobalt(II) complexes
Copper(II) complexes
Crystal structures
Iron(II) complexes
Linear trinuclear complexes

Access to Document

10.1016/S1387-7003(98)00063-X

Cite this

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title = "Trinuclear complexes of copper, cobalt and iron with N,N′-di(2-pyridyl)formamidinate ligands, [M3(DPyF)4][PF6]2",

abstract = "Three isomorphous linear trinuclear complexes [M3(DPyF)4] [PF6]2·4CH3CN·2Et2O, M=Cu(II), Co(II), Fe(II), DPyF=N,N′-di(2-pyridyl) formamidinate, have been synthesized and their structures have been determined by single crystal X-ray crystallography. The structure of the cations in these compounds consists of a linear, symmetrical chain of metal atoms. The central metal atom is coordinated by four nitrogen atoms that form a ruffled planar array while the outer atoms are six-coordinate.",

keywords = "Cobalt(II) complexes, Copper(II) complexes, Crystal structures, Iron(II) complexes, Linear trinuclear complexes",

author = "Cotton, \{F. Albert\} and Murillo, \{Carlos A.\} and Xiaoping Wang",

year = "1998",

month = aug,

doi = "10.1016/S1387-7003(98)00063-X",

language = "English",

volume = "1",

pages = "281--283",

journal = "Inorganic Chemistry Communications",

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T1 - Trinuclear complexes of copper, cobalt and iron with N,N′-di(2-pyridyl)formamidinate ligands, [M3(DPyF)4][PF6]2

AU - Cotton, F. Albert

AU - Murillo, Carlos A.

AU - Wang, Xiaoping

PY - 1998/8

Y1 - 1998/8

N2 - Three isomorphous linear trinuclear complexes [M3(DPyF)4] [PF6]2·4CH3CN·2Et2O, M=Cu(II), Co(II), Fe(II), DPyF=N,N′-di(2-pyridyl) formamidinate, have been synthesized and their structures have been determined by single crystal X-ray crystallography. The structure of the cations in these compounds consists of a linear, symmetrical chain of metal atoms. The central metal atom is coordinated by four nitrogen atoms that form a ruffled planar array while the outer atoms are six-coordinate.

AB - Three isomorphous linear trinuclear complexes [M3(DPyF)4] [PF6]2·4CH3CN·2Et2O, M=Cu(II), Co(II), Fe(II), DPyF=N,N′-di(2-pyridyl) formamidinate, have been synthesized and their structures have been determined by single crystal X-ray crystallography. The structure of the cations in these compounds consists of a linear, symmetrical chain of metal atoms. The central metal atom is coordinated by four nitrogen atoms that form a ruffled planar array while the outer atoms are six-coordinate.

KW - Cobalt(II) complexes

KW - Copper(II) complexes

KW - Crystal structures

KW - Iron(II) complexes

KW - Linear trinuclear complexes

UR - https://www.scopus.com/pages/publications/0001478882

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DO - 10.1016/S1387-7003(98)00063-X

M3 - Article

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VL - 1

SP - 281

EP - 283

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

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