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Trichloroethylene replacements for the cleaning of silicone oil used in the internal gelation process

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Abstract

Silicone oil continues to be used as a gelation medium for internal gelation process. Typically, the silicone oil has been removed from the gel spheres using trichloroethylene (TCE) washes. However, TCE is no longer a viable option for large-scale operations because of environmental issues, health concerns, and disposal costs. During the development of a large gelation system at the Y-12 National Security Complex, two new TCE wash replacements were identified. NuSolv SOR-C and FluoSolv WS were used in a number of uranium runs and found to effectively remove silicone oil. NuSolv SOR-C was determined to be the best option.

Original languageEnglish
Article number153379
JournalJournal of Nuclear Materials
Volume558
DOIs
StatePublished - Jan 2022

Funding

This material is based upon work supported by the U.S. Department of Energy through contracts with Consolidated Nuclear Security, LLC and UT-Battelle, LLC. The work was performed at the Y-12 National Security Complex under the auspices of the Development Division. Additional work was performed at the ORNL under the auspices of theNuclear Energy and Fuel Cycle Division.

Keywords

  • Internal gelation
  • Trichloroethylene replacement
  • Uranium microspheres

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