trans-diaquabis(2,2′-bipyridine-N,N′)-ruthenium(II) bis(hexafluorophosphate)

Norman R. Weathers; Robert C. Sadoski; Bill Durham; A. Wallace Cordes

doi:10.1107/S0108270197004381

trans-diaquabis(2,2′-bipyridine-N,N′)-ruthenium(II) bis(hexafluorophosphate)

Norman R. Weathers, Robert C. Sadoski, Bill Durham, A. Wallace Cordes

HPC Clusters

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11 Scopus citations

Abstract

The Ru atom of the title complex, [Ru(C₁₀H₈N₂)₂-(H₂O) ₂](PF₆)₂, is located on a crystallographic inversion center; the bipyridine ligands are bowed [dihedral angle between C₅N planes is 162.68(12)°] due to the interligand steric interactions of the trans bipyridyl units. The Ru-O distance is 2.116 (2) Å and the mean Ru-N distance is 2.074 (2) Å.

Original language	English
Pages (from-to)	1047-1049
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	53
Issue number	8
DOIs	https://doi.org/10.1107/S0108270197004381
State	Published - Aug 15 1997

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title = "trans-diaquabis(2,2′-bipyridine-N,N′)-ruthenium(II) bis(hexafluorophosphate)",

abstract = "The Ru atom of the title complex, [Ru(C10H8N2)2-(H2O) 2](PF6)2, is located on a crystallographic inversion center; the bipyridine ligands are bowed [dihedral angle between C5N planes is 162.68(12)°] due to the interligand steric interactions of the trans bipyridyl units. The Ru-O distance is 2.116 (2) {\AA} and the mean Ru-N distance is 2.074 (2) {\AA}.",

author = "Weathers, {Norman R.} and Sadoski, {Robert C.} and Bill Durham and Cordes, {A. Wallace}",

year = "1997",

month = aug,

day = "15",

doi = "10.1107/S0108270197004381",

language = "English",

volume = "53",

pages = "1047--1049",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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TY - JOUR

T1 - trans-diaquabis(2,2′-bipyridine-N,N′)-ruthenium(II) bis(hexafluorophosphate)

AU - Weathers, Norman R.

AU - Sadoski, Robert C.

AU - Durham, Bill

AU - Cordes, A. Wallace

PY - 1997/8/15

Y1 - 1997/8/15

N2 - The Ru atom of the title complex, [Ru(C10H8N2)2-(H2O) 2](PF6)2, is located on a crystallographic inversion center; the bipyridine ligands are bowed [dihedral angle between C5N planes is 162.68(12)°] due to the interligand steric interactions of the trans bipyridyl units. The Ru-O distance is 2.116 (2) Å and the mean Ru-N distance is 2.074 (2) Å.

AB - The Ru atom of the title complex, [Ru(C10H8N2)2-(H2O) 2](PF6)2, is located on a crystallographic inversion center; the bipyridine ligands are bowed [dihedral angle between C5N planes is 162.68(12)°] due to the interligand steric interactions of the trans bipyridyl units. The Ru-O distance is 2.116 (2) Å and the mean Ru-N distance is 2.074 (2) Å.

UR - http://www.scopus.com/inward/record.url?scp=0031213409&partnerID=8YFLogxK

U2 - 10.1107/S0108270197004381

DO - 10.1107/S0108270197004381

M3 - Article

C2 - 9276918

AN - SCOPUS:0031213409

SN - 0108-2701

VL - 53

SP - 1047

EP - 1049

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 8

ER -

trans-diaquabis(2,2′-bipyridine-N,N′)-ruthenium(II) bis(hexafluorophosphate)

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