Abstract
We present the first use of in situ far-infrared spectroscopy to analyze the thermal amorphization of a zeolitic imidazolate framework material. We explain the nature of vibrational motion changes during the amorphization process and reveal new insights into the effect that temperature has on the Zn-N tetrahedra.
| Original language | English |
|---|---|
| Pages (from-to) | 7041-7044 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 53 |
| Issue number | 52 |
| DOIs | |
| State | Published - 2017 |
| Externally published | Yes |
Funding
M. R. R. would like to thank the UK Engineering and Physical Sciences Research Council (EPSRC) for a DTA postgraduate scholarship and an additional scholarship from the Science and Technology Facilities Council (STFC) CMSD Award 13-05. M. R. R. would also like to thank the EPSRC for a Doctoral Prize Fellowship. The experimental work was performed at Diamond through beamtime (SM10215) on the B22 MIRIAM beamline.
| Funders | Funder number |
|---|---|
| Engineering and Physical Sciences Research Council | |
| Science and Technology Facilities Council | 13-05, SM10215 |