Towards "mechanochemistry": Mechanically induced isomerizations of thiolate-gold clusters

Daniel Krüger; Roger Rousseau; Harald Fuchs; Dominik Marx

doi:10.1002/anie.200351000

Towards "mechanochemistry": Mechanically induced isomerizations of thiolate-gold clusters

Daniel Krüger
, Roger Rousseau
, Harald Fuchs
, Dominik Marx

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

Stretching the imagination: Based on simulations it is proposed that atommanipulation techniques, such as atomic force microscopy (AFM), could be used t, draw and manipulate monoatomic nano wires using thiolates anchored to gold clusters on surfaces (see picture, gold Au, yellow S). At the same time, the forceversus-extension curve is diagnostic for the isomerizations of the underlying covalently bound species.

Original language	English
Pages (from-to)	2251-2253
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	20
DOIs	https://doi.org/10.1002/anie.200351000
State	Published - May 25 2003
Externally published	Yes

Keywords

Chemisorption
Cluster compounds
Gold
Molecular electronics
Nanostructures

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10.1002/anie.200351000

Cite this

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abstract = "Stretching the imagination: Based on simulations it is proposed that atommanipulation techniques, such as atomic force microscopy (AFM), could be used t, draw and manipulate monoatomic nano wires using thiolates anchored to gold clusters on surfaces (see picture, gold Au, yellow S). At the same time, the forceversus-extension curve is diagnostic for the isomerizations of the underlying covalently bound species.",

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AU - Rousseau, Roger

AU - Fuchs, Harald

AU - Marx, Dominik

PY - 2003/5/25

Y1 - 2003/5/25

N2 - Stretching the imagination: Based on simulations it is proposed that atommanipulation techniques, such as atomic force microscopy (AFM), could be used t, draw and manipulate monoatomic nano wires using thiolates anchored to gold clusters on surfaces (see picture, gold Au, yellow S). At the same time, the forceversus-extension curve is diagnostic for the isomerizations of the underlying covalently bound species.

AB - Stretching the imagination: Based on simulations it is proposed that atommanipulation techniques, such as atomic force microscopy (AFM), could be used t, draw and manipulate monoatomic nano wires using thiolates anchored to gold clusters on surfaces (see picture, gold Au, yellow S). At the same time, the forceversus-extension curve is diagnostic for the isomerizations of the underlying covalently bound species.

KW - Chemisorption

KW - Cluster compounds

KW - Gold

KW - Molecular electronics

KW - Nanostructures

UR - https://www.scopus.com/pages/publications/0037981649

U2 - 10.1002/anie.200351000

DO - 10.1002/anie.200351000

M3 - Article

AN - SCOPUS:0037981649

SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 20

ER -

Towards "mechanochemistry": Mechanically induced isomerizations of thiolate-gold clusters

Abstract

Keywords

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