TICT fluorescence of N-borylated 2,5-diarylpyrroles: A gear like dual motion in the excited state

Takuhiro Taniguchi; Jian Wang; Stephan Irle; Shigehiro Yamaguchi

doi:10.1039/c2dt32134c

TICT fluorescence of N-borylated 2,5-diarylpyrroles: A gear like dual motion in the excited state

Takuhiro Taniguchi
, Jian Wang
, Stephan Irle
, Shigehiro Yamaguchi

Research output: Contribution to journal › Comment/debate

68 Scopus citations

Abstract

A significantly red-shifted fluorescence and a high fluorescence quantum yield for the emission from the twisted intramolecular charge transfer (TICT) state are attained in new aminoboranes, N-borylated 2,5-diarylpyrroles. A gear like dual structural motion in the excited state is responsible for their large Stokes shifts.

Original language	English
Pages (from-to)	620-624
Number of pages	5
Journal	Dalton Transactions
Volume	42
Issue number	2
DOIs	https://doi.org/10.1039/c2dt32134c
State	Published - 2013
Externally published	Yes

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@article{0d38f452923a4e99a8462f8e456a8655,

title = "TICT fluorescence of N-borylated 2,5-diarylpyrroles: A gear like dual motion in the excited state",

abstract = "A significantly red-shifted fluorescence and a high fluorescence quantum yield for the emission from the twisted intramolecular charge transfer (TICT) state are attained in new aminoboranes, N-borylated 2,5-diarylpyrroles. A gear like dual structural motion in the excited state is responsible for their large Stokes shifts.",

author = "Takuhiro Taniguchi and Jian Wang and Stephan Irle and Shigehiro Yamaguchi",

year = "2013",

doi = "10.1039/c2dt32134c",

language = "English",

volume = "42",

pages = "620--624",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - TICT fluorescence of N-borylated 2,5-diarylpyrroles

T2 - A gear like dual motion in the excited state

AU - Taniguchi, Takuhiro

AU - Wang, Jian

AU - Irle, Stephan

AU - Yamaguchi, Shigehiro

PY - 2013

Y1 - 2013

N2 - A significantly red-shifted fluorescence and a high fluorescence quantum yield for the emission from the twisted intramolecular charge transfer (TICT) state are attained in new aminoboranes, N-borylated 2,5-diarylpyrroles. A gear like dual structural motion in the excited state is responsible for their large Stokes shifts.

AB - A significantly red-shifted fluorescence and a high fluorescence quantum yield for the emission from the twisted intramolecular charge transfer (TICT) state are attained in new aminoboranes, N-borylated 2,5-diarylpyrroles. A gear like dual structural motion in the excited state is responsible for their large Stokes shifts.

UR - https://www.scopus.com/pages/publications/84871273753

U2 - 10.1039/c2dt32134c

DO - 10.1039/c2dt32134c

M3 - Comment/debate

AN - SCOPUS:84871273753

SN - 1477-9226

VL - 42

SP - 620

EP - 624

JO - Dalton Transactions

JF - Dalton Transactions

IS - 2

ER -

TICT fluorescence of N-borylated 2,5-diarylpyrroles: A gear like dual motion in the excited state

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