Three-liquid-phase extraction and separation of V(V) and Cr(VI) from acidic leach solutions of high-chromium vanadium–titanium magnetite

Pan Sun, Kun Huang, Xiaoqin Wang, Na Sui, Jieyuan Lin, Wenjuan Cao, Huizhou Liu

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

A new method by liquid–liquid–liquid three phase system, consisting of acidified primary amine N1923 (abbreviated as A-N1923), poly(ethylene glycol) (PEG) and (NH4)2SO4 aqueous solution, was suggested for the separation and simultaneous extraction of V(V) and Cr(VI) from the acidic leach solutions of high-chromium vanadium–titanium magnetite. Experimental results indicated that V(V) and Cr(VI) could be selectively enriched into the A-N1923 organic top phase and PEG-rich middle phase, respectively, while Al(III) and other co-existing impurity ions, such as Si(IV), Fe(III), Ti(IV), Mg(II) and Ca(II) in acidic leach solutions, could be enriched in the (NH4)2SO4 bottom aqueous phase. During the process for extraction and separation of V(V) and Cr(VI), almost all of impurity ions could be removed. The separation factors between V(V) and Cr(VI) could reach 630 and 908, respectively in the organic top phase and PEG middle phase, and yields of recovered V(V) and Cr(VI) in the top phase and middle phase respectively were all above 90%. Various effects including aqueous pH, A-N1923 concentration, PEG added amount and (NH4)2SO4 concentration on three-phase partitioning of V(V) and Cr(VI) were discussed. It was found that the partition of Cr(VI) into the PEG-rich middle phase was driven by hydrophobic interaction, while extraction of V(V) by A-N1923 resulted of anion exchange between NO3 and H2V10O28 4 −. Stripping of V(V) and Cr(VI) from the top organic phase and the middle PEG-rich phase were achieved by mixing respectively with NaNO3 aqueous solutions and NaOH-(NH4)2SO4 solutions. The present work highlights a new approach for the extraction and purification of V and Cr from the complex multi-metal co-existing acidic leach solutions of high-chromium vanadium–titanium magnetite.

Original languageEnglish
Pages (from-to)1451-1457
Number of pages7
JournalChinese Journal of Chemical Engineering
Volume26
Issue number7
DOIs
StatePublished - Jul 2018
Externally publishedYes

Funding

Supported by the National Basic Research and Development Program of China (973 Program; No. 2013CB632602 ), and the National Natural Science Foundation of China (Nos. 51574213 , 51074150 ).

FundersFunder number
National Basic Research and Development Program of China (973 Program2013CB632602
National Natural Science Foundation of China51574213, 51074150

    Keywords

    • Chromium
    • High-chromium vanadium–titanium magnetite
    • Separation
    • Three-liquid-phase extraction
    • Vanadium

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