Thermal dehydration and vibrational studies of ZnK4(P 3O9)2·6H2O

A. Abouimrane; K. Sbai

doi:10.1080/00387010600812574

Thermal dehydration and vibrational studies of ZnK₄(P ₃O₉)₂·6H₂O

A. Abouimrane
, K. Sbai

Emerging and Solid-State Batteries

Research output: Contribution to journal › Article › peer-review

Abstract

The thermal dehydration of ZnK₄(P₃O₉) ₂·6H₂O was studied in the range 25-500°C by thermogravimetric analysis (TGA and DSC) and X-ray diffraction. We found, based on the TGA and DSC scans, the dehydration of this salt takes place in three stages with a loss of the six water molecules. The infrared and Raman spectra of ZnK₄(P₃O₉)₂·6H₂O have been recorded and interpreted using a factor group analysis. The internal modes are assigned in terms of POP and PO₂ structural units using experimental and theoretical IR and Raman frequencies.

Original language	English
Pages (from-to)	421-429
Number of pages	9
Journal	Spectroscopy Letters
Volume	39
Issue number	5
DOIs	https://doi.org/10.1080/00387010600812574
State	Published - Oct 1 2006

Keywords

Cyclotriphosphate
DSC
Infrared (IR)
Raman spectroscopies
TGA
Thermal behavior

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10.1080/00387010600812574

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title = "Thermal dehydration and vibrational studies of ZnK4(P 3O9)2·6H2O",

abstract = "The thermal dehydration of ZnK4(P3O9) 2·6H2O was studied in the range 25-500°C by thermogravimetric analysis (TGA and DSC) and X-ray diffraction. We found, based on the TGA and DSC scans, the dehydration of this salt takes place in three stages with a loss of the six water molecules. The infrared and Raman spectra of ZnK4(P3O9)2·6H2O have been recorded and interpreted using a factor group analysis. The internal modes are assigned in terms of POP and PO2 structural units using experimental and theoretical IR and Raman frequencies.",

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T1 - Thermal dehydration and vibrational studies of ZnK4(P 3O9)2·6H2O

AU - Abouimrane, A.

AU - Sbai, K.

PY - 2006/10/1

Y1 - 2006/10/1

N2 - The thermal dehydration of ZnK4(P3O9) 2·6H2O was studied in the range 25-500°C by thermogravimetric analysis (TGA and DSC) and X-ray diffraction. We found, based on the TGA and DSC scans, the dehydration of this salt takes place in three stages with a loss of the six water molecules. The infrared and Raman spectra of ZnK4(P3O9)2·6H2O have been recorded and interpreted using a factor group analysis. The internal modes are assigned in terms of POP and PO2 structural units using experimental and theoretical IR and Raman frequencies.

AB - The thermal dehydration of ZnK4(P3O9) 2·6H2O was studied in the range 25-500°C by thermogravimetric analysis (TGA and DSC) and X-ray diffraction. We found, based on the TGA and DSC scans, the dehydration of this salt takes place in three stages with a loss of the six water molecules. The infrared and Raman spectra of ZnK4(P3O9)2·6H2O have been recorded and interpreted using a factor group analysis. The internal modes are assigned in terms of POP and PO2 structural units using experimental and theoretical IR and Raman frequencies.

KW - Cyclotriphosphate

KW - DSC

KW - Infrared (IR)

KW - Raman spectroscopies

KW - TGA

KW - Thermal behavior

UR - https://www.scopus.com/pages/publications/33748453220

U2 - 10.1080/00387010600812574

DO - 10.1080/00387010600812574

M3 - Article

AN - SCOPUS:33748453220

SN - 0038-7010

VL - 39

SP - 421

EP - 429

JO - Spectroscopy Letters

JF - Spectroscopy Letters

IS - 5

ER -

Thermal dehydration and vibrational studies of ZnK₄(P ₃O₉)₂·6H₂O

Abstract

Keywords

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