Theoretical studies on the structure of interacting colloidal suspensions by spin-echo small angle neutron scattering

Xin Li, Chwen Yang Shew, Yun Liu, Roger Pynn, Emily Liu, Kenneth W. Herwig, Gregory S. Smith, J. Lee Robertson, Wei Ren Chen

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

The application of the spin-echo small angle neutron scattering (SESANS) technique for structural characterization of interacting colloidal suspensions is considered in this work. The framework to calculate the theoretical SESANS correlation function is briefly laid out. A general discussion regarding the features of the SESANS correlation functions obtained from different model systems is presented. In comparison with conventional elastic scattering tools operating at the same length scale, our mean-field calculations, based on a monodisperse spherical colloidal system, show that the real-space measurement provided by SESANS presents a powerful probe for studying the intercolloid potential. The reason of this sensitivity is discussed from the standpoint of way, in which how the spatial correlations are manifested in different neutron scattering implementations. This study leads to a better understanding regarding the distinction between SANS and SESANS.

Original languageEnglish
Article number174509
JournalJournal of Chemical Physics
Volume132
Issue number17
DOIs
StatePublished - May 7 2010

Funding

We thank the support of the ORNL-LDRD program (Project No. 05272). C.Y.S. was partially supported by the PSC grants of the City University of New York. R.P. was supported by the Department of Energy through its Office of Basic Energy Sciences, Division of Material Science and Engineering (Grant No. ER46279). X.L. and E.L. were supported in part by the U.S. Department of Energy, under NERI-C Award No. DE-FG07-07ID14889, and U.S. Nuclear Regulatory Commission, under Award No. NRC-38-08-950.

FundersFunder number
Division of Material Science and Engineering
ORNL-LDRD05272
U.S. Department of Energy
Basic Energy Sciences
City University of New York
PSC Partners Seeking a Cure

    Fingerprint

    Dive into the research topics of 'Theoretical studies on the structure of interacting colloidal suspensions by spin-echo small angle neutron scattering'. Together they form a unique fingerprint.

    Cite this