The role of surface basal planes of layered mixed metal oxides in selective transformation of lower alkanes: Propane ammoxidation over surface ab planes of Mo-V-Te-Nb-O M1 phase

N. Raveendran Shiju; Xinhua Liang; Alan W. Weimer; Chengdu Liang; Sheng Dai; Vadim V. Guliants

doi:10.1021/ja800575v

The role of surface basal planes of layered mixed metal oxides in selective transformation of lower alkanes: Propane ammoxidation over surface ab planes of Mo-V-Te-Nb-O M1 phase

N. Raveendran Shiju, Xinhua Liang, Alan W. Weimer, Chengdu Liang, Sheng Dai, Vadim V. Guliants

Chemical Sciences Division

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

The surface ab planes of the M1 phase exposed selectively after atomic layer deposition (ALD) of alumina followed by crushing showed significantly improved selectivity to acrylonitrile during propane ammoxidation. The results demonstrated the importance of surface ab planes for the activity and selectivity of the M1 phase in propane ammoxidation and general utility of surface modification by ALD in studies of catalytic behavior of surface planes in layered mixed metal oxides.

Original language	English
Pages (from-to)	5850-5851
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	18
DOIs	https://doi.org/10.1021/ja800575v
State	Published - May 7 2008

Access to Document

10.1021/ja800575v

Cite this

@article{487f22db979d425392e31e74147f032f,

title = "The role of surface basal planes of layered mixed metal oxides in selective transformation of lower alkanes: Propane ammoxidation over surface ab planes of Mo-V-Te-Nb-O M1 phase",

abstract = "The surface ab planes of the M1 phase exposed selectively after atomic layer deposition (ALD) of alumina followed by crushing showed significantly improved selectivity to acrylonitrile during propane ammoxidation. The results demonstrated the importance of surface ab planes for the activity and selectivity of the M1 phase in propane ammoxidation and general utility of surface modification by ALD in studies of catalytic behavior of surface planes in layered mixed metal oxides.",

author = "Shiju, {N. Raveendran} and Xinhua Liang and Weimer, {Alan W.} and Chengdu Liang and Sheng Dai and Guliants, {Vadim V.}",

year = "2008",

month = may,

day = "7",

doi = "10.1021/ja800575v",

language = "English",

volume = "130",

pages = "5850--5851",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "18",

}

The role of surface basal planes of layered mixed metal oxides in selective transformation of lower alkanes: Propane ammoxidation over surface ab planes of Mo-V-Te-Nb-O M1 phase. / Shiju, N. Raveendran; Liang, Xinhua; Weimer, Alan W. et al.
In: Journal of the American Chemical Society, Vol. 130, No. 18, 07.05.2008, p. 5850-5851.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The role of surface basal planes of layered mixed metal oxides in selective transformation of lower alkanes

T2 - Propane ammoxidation over surface ab planes of Mo-V-Te-Nb-O M1 phase

AU - Shiju, N. Raveendran

AU - Liang, Xinhua

AU - Weimer, Alan W.

AU - Liang, Chengdu

AU - Dai, Sheng

AU - Guliants, Vadim V.

PY - 2008/5/7

Y1 - 2008/5/7

N2 - The surface ab planes of the M1 phase exposed selectively after atomic layer deposition (ALD) of alumina followed by crushing showed significantly improved selectivity to acrylonitrile during propane ammoxidation. The results demonstrated the importance of surface ab planes for the activity and selectivity of the M1 phase in propane ammoxidation and general utility of surface modification by ALD in studies of catalytic behavior of surface planes in layered mixed metal oxides.

AB - The surface ab planes of the M1 phase exposed selectively after atomic layer deposition (ALD) of alumina followed by crushing showed significantly improved selectivity to acrylonitrile during propane ammoxidation. The results demonstrated the importance of surface ab planes for the activity and selectivity of the M1 phase in propane ammoxidation and general utility of surface modification by ALD in studies of catalytic behavior of surface planes in layered mixed metal oxides.

UR - http://www.scopus.com/inward/record.url?scp=42949175113&partnerID=8YFLogxK

U2 - 10.1021/ja800575v

DO - 10.1021/ja800575v

M3 - Article

AN - SCOPUS:42949175113

SN - 0002-7863

VL - 130

SP - 5850

EP - 5851

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 18

ER -

The role of surface basal planes of layered mixed metal oxides in selective transformation of lower alkanes: Propane ammoxidation over surface ab planes of Mo-V-Te-Nb-O M1 phase

Abstract

Access to Document

Other files and links

Fingerprint

Cite this