The role of O(1D) in the oxidation mechanism of ethylene by iodosobenzene and other hypervalent molecules

Shahriar N. Khan; Evangelos Miliordos

doi:10.1039/c7cp04000h

The role of O(¹D) in the oxidation mechanism of ethylene by iodosobenzene and other hypervalent molecules

Shahriar N. Khan
, Evangelos Miliordos

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The role of the first excited state of oxygen (¹D) is proven essential for the description of terminal iodine-oxygen chemical bonds. The description of the I-O bond as a dative one from iodine to O(¹D) provides a simple and accurate picture which explains the oxidation properties of iodosobenzene and similar in nature molecules.

Original language	English
Pages (from-to)	18152-18155
Number of pages	4
Journal	Physical Chemistry Chemical Physics
Volume	19
Issue number	28
DOIs	https://doi.org/10.1039/c7cp04000h
State	Published - 2017
Externally published	Yes

Funding

The authors are indebted to Auburn University for financial support.

Access to Document

10.1039/c7cp04000h

Cite this

@article{483b63a6ede447e39fad64620b872818,

title = "The role of O(1D) in the oxidation mechanism of ethylene by iodosobenzene and other hypervalent molecules",

abstract = "The role of the first excited state of oxygen (1D) is proven essential for the description of terminal iodine-oxygen chemical bonds. The description of the I-O bond as a dative one from iodine to O(1D) provides a simple and accurate picture which explains the oxidation properties of iodosobenzene and similar in nature molecules.",

author = "Khan, \{Shahriar N.\} and Evangelos Miliordos",

note = "Publisher Copyright: {\textcopyright} the Owner Societies 2017.",

year = "2017",

doi = "10.1039/c7cp04000h",

language = "English",

volume = "19",

pages = "18152--18155",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

number = "28",

}

TY - JOUR

T1 - The role of O(1D) in the oxidation mechanism of ethylene by iodosobenzene and other hypervalent molecules

AU - Khan, Shahriar N.

AU - Miliordos, Evangelos

N1 - Publisher Copyright: © the Owner Societies 2017.

PY - 2017

Y1 - 2017

N2 - The role of the first excited state of oxygen (1D) is proven essential for the description of terminal iodine-oxygen chemical bonds. The description of the I-O bond as a dative one from iodine to O(1D) provides a simple and accurate picture which explains the oxidation properties of iodosobenzene and similar in nature molecules.

AB - The role of the first excited state of oxygen (1D) is proven essential for the description of terminal iodine-oxygen chemical bonds. The description of the I-O bond as a dative one from iodine to O(1D) provides a simple and accurate picture which explains the oxidation properties of iodosobenzene and similar in nature molecules.

UR - https://www.scopus.com/pages/publications/85026236261

U2 - 10.1039/c7cp04000h

DO - 10.1039/c7cp04000h

M3 - Article

C2 - 28692086

AN - SCOPUS:85026236261

SN - 1463-9076

VL - 19

SP - 18152

EP - 18155

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 28

ER -

The role of O(¹D) in the oxidation mechanism of ethylene by iodosobenzene and other hypervalent molecules

Abstract

Funding

Access to Document

Other files and links

Fingerprint

Cite this