The new heteropolyoxometalate compound (C6H8N)5[HAs2Mo6O26(H2O)]·3H2O: Crystal structure and hirshfeld surface analysis

Ali Harchani; Damian Trzybiński; Sylwia Pawlędzio; Krzysztof Woźniak; Amor Haddad

doi:10.1107/S2053229618012317

The new heteropolyoxometalate compound (C₆H₈N)₅[HAs₂Mo₆O₂₆(H₂O)]·3H₂O: Crystal structure and hirshfeld surface analysis

Ali Harchani, Damian Trzybiński, Sylwia Pawlędzio, Krzysztof Woźniak, Amor Haddad

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A detailed description of the crystal structure and a Hirshfeld surface analysis of the new heteropolyoxometalate compound (C₆H₈N)₅[HAs₂Mo₆O₂₆(H₂O)]·3H₂O are reported. The title compound was synthesized using solution methods and its structure was characterized by single-crystal X-ray diffraction. The investigated compound contains a new [HAs₂Mo₆O₂₆(H₂O)]^5- polyanion and crystallizes in the monoclinic space group P2₁/c. The crystallographic analysis provided an understanding of the architecture and structural features of the complex crystal lattice and the Hirshfeld surface analysis shed more light on the intermolecular interactions occurring in the crystal.

Original language	English
Pages (from-to)	1088-1093
Number of pages	6
Journal	Acta Crystallographica Section C: Structural Chemistry
Volume	74
DOIs	https://doi.org/10.1107/S2053229618012317
State	Published - 2018
Externally published	Yes

Funding

The crystallographic part was carried out at the Biological and Chemical Research Centre, University of Warsaw, established within the project co-financed by the European Union via the European Regional Development Fund under the Operational Programme Innovative Economy, 2007–2013. The X-ray measurements and analysis of data were carried out at the Core Facility for Crystallography and Biophysics (CFCB) within the project ‘Core facility for crystallographic and biophysical research to support the development of medicinal products’ funded by the TEAM–TECH Core Facility programme from the Foundation for Polish Science. Funding for this research was provided by: Ministère de l’Enseignement Supérieur et de la Recherche Scientifique; Fundacja na rzecz Nauki Polskiej.

Funders	Funder number
Ministère de l’Enseignement Supérieur et de la Recherche Scientifique
European Commission
Fundacja na rzecz Nauki Polskiej
European Regional Development Fund

Keywords

Arsenic molybdate
Crystal structure
Hirshfeld surface
POM
Polyoxometalate

Access to Document

10.1107/S2053229618012317

Cite this

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title = "The new heteropolyoxometalate compound (C6H8N)5[HAs2Mo6O26(H2O)]·3H2O: Crystal structure and hirshfeld surface analysis",

abstract = "A detailed description of the crystal structure and a Hirshfeld surface analysis of the new heteropolyoxometalate compound (C6H8N)5[HAs2Mo6O26(H2O)]·3H2O are reported. The title compound was synthesized using solution methods and its structure was characterized by single-crystal X-ray diffraction. The investigated compound contains a new [HAs2Mo6O26(H2O)]5- polyanion and crystallizes in the monoclinic space group P21/c. The crystallographic analysis provided an understanding of the architecture and structural features of the complex crystal lattice and the Hirshfeld surface analysis shed more light on the intermolecular interactions occurring in the crystal.",

keywords = "Arsenic molybdate, Crystal structure, Hirshfeld surface, POM, Polyoxometalate",

author = "Ali Harchani and Damian Trzybi{\'n}ski and Sylwia Pawl{\c e}dzio and Krzysztof Wo{\'z}niak and Amor Haddad",

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T2 - Crystal structure and hirshfeld surface analysis

AU - Harchani, Ali

AU - Trzybiński, Damian

AU - Pawlędzio, Sylwia

AU - Woźniak, Krzysztof

AU - Haddad, Amor

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AB - A detailed description of the crystal structure and a Hirshfeld surface analysis of the new heteropolyoxometalate compound (C6H8N)5[HAs2Mo6O26(H2O)]·3H2O are reported. The title compound was synthesized using solution methods and its structure was characterized by single-crystal X-ray diffraction. The investigated compound contains a new [HAs2Mo6O26(H2O)]5- polyanion and crystallizes in the monoclinic space group P21/c. The crystallographic analysis provided an understanding of the architecture and structural features of the complex crystal lattice and the Hirshfeld surface analysis shed more light on the intermolecular interactions occurring in the crystal.

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KW - POM

KW - Polyoxometalate

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