The M(dddt)2 family of conducting complexes: [Ni(dddt)2]3(AuBr2)2, the first quasi-two-dimensional metal stable down to at least 1.3 K

Lyudmila A. Kushch; Viktor V. Gritsenko; Lev I. Buravov; Anna G. Khomenko; Gennadii V. Shilov; Oleg A. Dyachenko; Vladimir A. Merzhanov; Eduard B. Yagubskii; Roger Rousseau; Enric Canadell

doi:10.1039/JM9950501633

The M(dddt)₂ family of conducting complexes: [Ni(dddt)₂]₃(AuBr₂)₂, the first quasi-two-dimensional metal stable down to at least 1.3 K

Lyudmila A. Kushch
, Viktor V. Gritsenko
, Lev I. Buravov
, Anna G. Khomenko
, Gennadii V. Shilov
, Oleg A. Dyachenko
, Vladimir A. Merzhanov
, Eduard B. Yagubskii
, Roger Rousseau
, Enric Canadell

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

The first stable molecular metal, [Ni(dddt₂]₃(AuBr₂)₂, among the M(dddt)₂ family of conducting charge-transfer salts has been prepared and its crystal structure has been solved by X-ray analysis. The origin of the metallic conductivity of [Ni(dddt)₂]₃(AuBr₂)₂ as well as the stability of this salt with respect to metal-to-insulator transitions is explained on the basis of tight-binding band structure calculations.

Original language	English
Pages (from-to)	1633-1638
Number of pages	6
Journal	Journal of Materials Chemistry
Volume	5
Issue number	10
DOIs	https://doi.org/10.1039/JM9950501633
State	Published - 1995
Externally published	Yes

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Kushch, L. A., Gritsenko, V. V., Buravov, L. I., Khomenko, A. G., Shilov, G. V., Dyachenko, O. A., Merzhanov, V. A., Yagubskii, E. B., Rousseau, R., & Canadell, E. (1995). The M(dddt)₂ family of conducting complexes: [Ni(dddt)₂]₃(AuBr₂)₂, the first quasi-two-dimensional metal stable down to at least 1.3 K. Journal of Materials Chemistry, 5(10), 1633-1638. https://doi.org/10.1039/JM9950501633

@article{f10d6b0ecad7417eb44b4a4c499193ca,

title = "The M(dddt)2 family of conducting complexes: [Ni(dddt)2]3(AuBr2)2, the first quasi-two-dimensional metal stable down to at least 1.3 K",

abstract = "The first stable molecular metal, [Ni(dddt2]3(AuBr2)2, among the M(dddt)2 family of conducting charge-transfer salts has been prepared and its crystal structure has been solved by X-ray analysis. The origin of the metallic conductivity of [Ni(dddt)2]3(AuBr2)2 as well as the stability of this salt with respect to metal-to-insulator transitions is explained on the basis of tight-binding band structure calculations.",

author = "Kushch, \{Lyudmila A.\} and Gritsenko, \{Viktor V.\} and Buravov, \{Lev I.\} and Khomenko, \{Anna G.\} and Shilov, \{Gennadii V.\} and Dyachenko, \{Oleg A.\} and Merzhanov, \{Vladimir A.\} and Yagubskii, \{Eduard B.\} and Roger Rousseau and Enric Canadell",

year = "1995",

doi = "10.1039/JM9950501633",

language = "English",

volume = "5",

pages = "1633--1638",

journal = "Journal of Materials Chemistry",

issn = "0959-9428",

number = "10",

}

Kushch, LA, Gritsenko, VV, Buravov, LI, Khomenko, AG, Shilov, GV, Dyachenko, OA, Merzhanov, VA, Yagubskii, EB, Rousseau, R & Canadell, E 1995, 'The M(dddt)₂ family of conducting complexes: [Ni(dddt)₂]₃(AuBr₂)₂, the first quasi-two-dimensional metal stable down to at least 1.3 K', Journal of Materials Chemistry, vol. 5, no. 10, pp. 1633-1638. https://doi.org/10.1039/JM9950501633

TY - JOUR

T1 - The M(dddt)2 family of conducting complexes

T2 - [Ni(dddt)2]3(AuBr2)2, the first quasi-two-dimensional metal stable down to at least 1.3 K

AU - Kushch, Lyudmila A.

AU - Gritsenko, Viktor V.

AU - Buravov, Lev I.

AU - Khomenko, Anna G.

AU - Shilov, Gennadii V.

AU - Dyachenko, Oleg A.

AU - Merzhanov, Vladimir A.

AU - Yagubskii, Eduard B.

AU - Rousseau, Roger

AU - Canadell, Enric

PY - 1995

Y1 - 1995

N2 - The first stable molecular metal, [Ni(dddt2]3(AuBr2)2, among the M(dddt)2 family of conducting charge-transfer salts has been prepared and its crystal structure has been solved by X-ray analysis. The origin of the metallic conductivity of [Ni(dddt)2]3(AuBr2)2 as well as the stability of this salt with respect to metal-to-insulator transitions is explained on the basis of tight-binding band structure calculations.

AB - The first stable molecular metal, [Ni(dddt2]3(AuBr2)2, among the M(dddt)2 family of conducting charge-transfer salts has been prepared and its crystal structure has been solved by X-ray analysis. The origin of the metallic conductivity of [Ni(dddt)2]3(AuBr2)2 as well as the stability of this salt with respect to metal-to-insulator transitions is explained on the basis of tight-binding band structure calculations.

UR - https://www.scopus.com/pages/publications/0000095466

U2 - 10.1039/JM9950501633

DO - 10.1039/JM9950501633

M3 - Article

AN - SCOPUS:0000095466

SN - 0959-9428

VL - 5

SP - 1633

EP - 1638

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

IS - 10

ER -

The M(dddt)₂ family of conducting complexes: [Ni(dddt)₂]₃(AuBr₂)₂, the first quasi-two-dimensional metal stable down to at least 1.3 K

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