TY - JOUR
T1 - The M(dddt)2 family of conducting complexes
T2 - [Ni(dddt)2]3(AuBr2)2, the first quasi-two-dimensional metal stable down to at least 1.3 K
AU - Kushch, Lyudmila A.
AU - Gritsenko, Viktor V.
AU - Buravov, Lev I.
AU - Khomenko, Anna G.
AU - Shilov, Gennadii V.
AU - Dyachenko, Oleg A.
AU - Merzhanov, Vladimir A.
AU - Yagubskii, Eduard B.
AU - Rousseau, Roger
AU - Canadell, Enric
PY - 1995
Y1 - 1995
N2 - The first stable molecular metal, [Ni(dddt2]3(AuBr2)2, among the M(dddt)2 family of conducting charge-transfer salts has been prepared and its crystal structure has been solved by X-ray analysis. The origin of the metallic conductivity of [Ni(dddt)2]3(AuBr2)2 as well as the stability of this salt with respect to metal-to-insulator transitions is explained on the basis of tight-binding band structure calculations.
AB - The first stable molecular metal, [Ni(dddt2]3(AuBr2)2, among the M(dddt)2 family of conducting charge-transfer salts has been prepared and its crystal structure has been solved by X-ray analysis. The origin of the metallic conductivity of [Ni(dddt)2]3(AuBr2)2 as well as the stability of this salt with respect to metal-to-insulator transitions is explained on the basis of tight-binding band structure calculations.
UR - http://www.scopus.com/inward/record.url?scp=0000095466&partnerID=8YFLogxK
U2 - 10.1039/JM9950501633
DO - 10.1039/JM9950501633
M3 - Article
AN - SCOPUS:0000095466
SN - 0959-9428
VL - 5
SP - 1633
EP - 1638
JO - Journal of Materials Chemistry
JF - Journal of Materials Chemistry
IS - 10
ER -