Abstract
The growth of Al2O3 scales on β-NiAl was studied at 1500°C. Oxidation rates, diffusion mechanisms, and microstructures were examined in order to achieve a complete understanding of the scale development. Variation of the Al content within the β phase field had little effect on the oxidation behavior. Ionimplanted yttrium (2×1016/cm2) was observed to provide a short-term improvement in scale adhesion but little long-term effect. When doped with Y or Zr, the first 1 μm of α-Al2O3 was observed to grow mainly by an inward oxygen growth mechanism. At longer times when the implant was ineffective, microstructural observations indicate a mixed-growth mode.
Original language | English |
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Pages (from-to) | 203-233 |
Number of pages | 31 |
Journal | Oxidation of Metals |
Volume | 41 |
Issue number | 3-4 |
DOIs | |
State | Published - Apr 1994 |
Externally published | Yes |
Keywords
- growth mechanism
- ion implantation
- reactive element effect
- α-AlO
- β-NiAl