The formation of α-Al2O3 scales at 1500°C

B. A. Pint, L. W. Hobbs

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Abstract

The growth of Al2O3 scales on β-NiAl was studied at 1500°C. Oxidation rates, diffusion mechanisms, and microstructures were examined in order to achieve a complete understanding of the scale development. Variation of the Al content within the β phase field had little effect on the oxidation behavior. Ionimplanted yttrium (2×1016/cm2) was observed to provide a short-term improvement in scale adhesion but little long-term effect. When doped with Y or Zr, the first 1 μm of α-Al2O3 was observed to grow mainly by an inward oxygen growth mechanism. At longer times when the implant was ineffective, microstructural observations indicate a mixed-growth mode.

Original languageEnglish
Pages (from-to)203-233
Number of pages31
JournalOxidation of Metals
Volume41
Issue number3-4
DOIs
StatePublished - Apr 1994
Externally publishedYes

Keywords

  • growth mechanism
  • ion implantation
  • reactive element effect
  • α-AlO
  • β-NiAl

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