TY - JOUR
T1 - The existence of memory effect on hydrogen ordering in ice
T2 - The effect makes ice attractive
AU - Arakawa, Masashi
AU - Kagi, Hiroyuki
AU - Fernandez-Baca, Jaime A.
AU - Chakoumakos, Bryan C.
AU - Fukazawa, Hiroshi
PY - 2011/8/1
Y1 - 2011/8/1
N2 - The existence of ferroelectric ice XI with ordered hydrogen in space becomes of interest in astronomy and physical chemistry because of the strong electrostatic force. However, the influence was believed to be limited because it forms in a narrow temperature range. From neutron diffraction experiments, we found that small hydrogen-ordered domains exist at significantly higher temperature and the domains induce the growth of "bulk" ice XI. The small ordered domain is named "memory" of hydrogen ordered ice because it is the residual structure of ice XI. Since the memory exists up to at least 111 K, most of ices in the solar system are hydrogen ordered and may have ferroelectricity. The small hydrogen-ordered domains govern the cosmochemical properties of ice and evolution of icy grains in the universe.
AB - The existence of ferroelectric ice XI with ordered hydrogen in space becomes of interest in astronomy and physical chemistry because of the strong electrostatic force. However, the influence was believed to be limited because it forms in a narrow temperature range. From neutron diffraction experiments, we found that small hydrogen-ordered domains exist at significantly higher temperature and the domains induce the growth of "bulk" ice XI. The small ordered domain is named "memory" of hydrogen ordered ice because it is the residual structure of ice XI. Since the memory exists up to at least 111 K, most of ices in the solar system are hydrogen ordered and may have ferroelectricity. The small hydrogen-ordered domains govern the cosmochemical properties of ice and evolution of icy grains in the universe.
UR - http://www.scopus.com/inward/record.url?scp=80051979143&partnerID=8YFLogxK
U2 - 10.1029/2011GL048217
DO - 10.1029/2011GL048217
M3 - Article
AN - SCOPUS:80051979143
SN - 0094-8276
VL - 38
JO - Geophysical Research Letters
JF - Geophysical Research Letters
IS - 16
M1 - L16101
ER -