Tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels for non-enzymatic glucose sensing

Krystian Lankauf; Katarzyna Ostrowska; Karolina Górnicka; Jakub Karczewski; Piotr Jasiński; Sebastian Molin

doi:10.1016/j.matlet.2022.132574

Tetrahedrally modified MnMe_0.1Co_1.9O₄ (Me = Zn, Mg, Li) spinels for non-enzymatic glucose sensing

Krystian Lankauf, Katarzyna Ostrowska, Karolina Górnicka, Jakub Karczewski, Piotr Jasiński, Sebastian Molin

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

In this work, tetrahedrally modified MnMe_0.1Co_1.9O₄ (Me = Zn, Mg, Li) spinels were prepared via the sol–gel synthesis method with subsequent ball-milling fragmentation. The prepared samples were evaluated as glucose–sensing catalyst. The reference MnCo₂O₄ spinel exhibited a sensitivity of 49 µA mM⁻¹ cm⁻² and a nonlinearity error of 5.2% in the response range from 0.02 to 1 mM. The partial substitution of cobalt in the reference spinel enhanced the glucose–sensing abilities, and the sample with Li was found to be the most active catalyst, exhibiting a sensitivity of 73.1 µA mM⁻¹ cm⁻². Finally, the proposed material was tested for selectivity in the presence of interfering sucrose.

Original language	English
Article number	132574
Journal	Materials Letters
Volume	323
DOIs	https://doi.org/10.1016/j.matlet.2022.132574
State	Published - Sep 15 2022
Externally published	Yes

Funding

The presented research is part of the “Nanocrystalline ceramic materials for efficient electrochemical energy conversion” project, carried out within the First TEAM programme of the Foundation for Polish Science (grant agreement nr. POIR.04.04.00-00-42E9/17-00), co–financed by the European Union under the European Regional Development Fund. Funding from the Statutory Funds of WETI PG is also acknowledged. This publication was developed under the provision of the Polish Ministry of Education and Science project: “Support for research and development with the use of research infrastructure of the National Synchrotron Radiation Centre SOLARIS” under contract nr. 1/SOL/2021/2. We acknowledge the SOLARIS Centre for the access to the Beamline PIRX, where the measurements were performed.

Keywords

Cation substitution
Glucose sensor
Spinel

Access to Document

10.1016/j.matlet.2022.132574

Cite this

@article{6122089236a64aab8d812f94c7863ea7,

title = "Tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels for non-enzymatic glucose sensing",

abstract = "In this work, tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels were prepared via the sol–gel synthesis method with subsequent ball-milling fragmentation. The prepared samples were evaluated as glucose–sensing catalyst. The reference MnCo2O4 spinel exhibited a sensitivity of 49 µA mM−1 cm−2 and a nonlinearity error of 5.2\% in the response range from 0.02 to 1 mM. The partial substitution of cobalt in the reference spinel enhanced the glucose–sensing abilities, and the sample with Li was found to be the most active catalyst, exhibiting a sensitivity of 73.1 µA mM−1 cm−2. Finally, the proposed material was tested for selectivity in the presence of interfering sucrose.",

keywords = "Cation substitution, Glucose sensor, Spinel",

author = "Krystian Lankauf and Katarzyna Ostrowska and Karolina G{\'o}rnicka and Jakub Karczewski and Piotr Jasi{\'n}ski and Sebastian Molin",

note = "Publisher Copyright: {\textcopyright} 2022 The Authors",

year = "2022",

month = sep,

day = "15",

doi = "10.1016/j.matlet.2022.132574",

language = "English",

volume = "323",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels for non-enzymatic glucose sensing

AU - Lankauf, Krystian

AU - Ostrowska, Katarzyna

AU - Górnicka, Karolina

AU - Karczewski, Jakub

AU - Jasiński, Piotr

AU - Molin, Sebastian

PY - 2022/9/15

Y1 - 2022/9/15

N2 - In this work, tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels were prepared via the sol–gel synthesis method with subsequent ball-milling fragmentation. The prepared samples were evaluated as glucose–sensing catalyst. The reference MnCo2O4 spinel exhibited a sensitivity of 49 µA mM−1 cm−2 and a nonlinearity error of 5.2% in the response range from 0.02 to 1 mM. The partial substitution of cobalt in the reference spinel enhanced the glucose–sensing abilities, and the sample with Li was found to be the most active catalyst, exhibiting a sensitivity of 73.1 µA mM−1 cm−2. Finally, the proposed material was tested for selectivity in the presence of interfering sucrose.

AB - In this work, tetrahedrally modified MnMe0.1Co1.9O4 (Me = Zn, Mg, Li) spinels were prepared via the sol–gel synthesis method with subsequent ball-milling fragmentation. The prepared samples were evaluated as glucose–sensing catalyst. The reference MnCo2O4 spinel exhibited a sensitivity of 49 µA mM−1 cm−2 and a nonlinearity error of 5.2% in the response range from 0.02 to 1 mM. The partial substitution of cobalt in the reference spinel enhanced the glucose–sensing abilities, and the sample with Li was found to be the most active catalyst, exhibiting a sensitivity of 73.1 µA mM−1 cm−2. Finally, the proposed material was tested for selectivity in the presence of interfering sucrose.

KW - Cation substitution

KW - Glucose sensor

KW - Spinel

UR - https://www.scopus.com/pages/publications/85131918204

U2 - 10.1016/j.matlet.2022.132574

DO - 10.1016/j.matlet.2022.132574

M3 - Article

AN - SCOPUS:85131918204

SN - 0167-577X

VL - 323

JO - Materials Letters

JF - Materials Letters

M1 - 132574

ER -