Tetra-μ-acetato-κ8O:O′-bis[(N1,N 2-di-p-anisylformamidine-κN2)ruthenium(II)]-(Ru - Ru): An example of an axial bis-adduct of {Ru2}4+ tetracarboxylate with N-donor ligands

Panagiotis Angaridis; F. Albert Cotton; Carlos A. Murillo; Xiao Ping Wang

doi:10.1107/S0108270104032494

Tetra-μ-acetato-κ⁸O:O′-bis[(N¹,N ²-di-p-anisylformamidine-κN²)ruthenium(II)]-(Ru - Ru): An example of an axial bis-adduct of {Ru₂}⁴⁺ tetracarboxylate with N-donor ligands

Panagiotis Angaridis
, F. Albert Cotton
, Carlos A. Murillo
, Xiao Ping Wang

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound, [Ru₂(C₂H₃O ₂)₄(C₁₅H₁₆N₂O ₂)₂], lies on a crystallographic inversion center and exhibits an Ru-Ru bond length of 2.2847 (8) Å. There are weak intramolecular hydrogen-bonding interactions between the N¹,N ²-di-p-anisyl-formamidine (HDAniF) ligands and the bridging acetate ligands. The molecule is one of the few examples of a crystallographically characterized axial bis-adduct of a (Ru₂}⁴⁺ complex with two N-donor ligands.

Original language	English
Pages (from-to)	m109-m111
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	61
Issue number	2
DOIs	https://doi.org/10.1107/S0108270104032494
State	Published - Feb 2005
Externally published	Yes

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Angaridis, P., Albert Cotton, F., Murillo, C. A., & Wang, X. P. (2005). Tetra-μ-acetato-κ⁸O:O′-bis[(N¹,N ²-di-p-anisylformamidine-κN²)ruthenium(II)]-(Ru - Ru): An example of an axial bis-adduct of {Ru₂}⁴⁺ tetracarboxylate with N-donor ligands. Acta Crystallographica Section C: Crystal Structure Communications, 61(2), m109-m111. https://doi.org/10.1107/S0108270104032494

@article{cdb8d3e63b4a449892e3e14180e3494c,

title = "Tetra-μ-acetato-κ8O:O′-bis[(N1,N 2-di-p-anisylformamidine-κN2)ruthenium(II)]-(Ru - Ru): An example of an axial bis-adduct of \{Ru2\}4+ tetracarboxylate with N-donor ligands",

abstract = "The title compound, [Ru2(C2H3O 2)4(C15H16N2O 2)2], lies on a crystallographic inversion center and exhibits an Ru-Ru bond length of 2.2847 (8) {\AA}. There are weak intramolecular hydrogen-bonding interactions between the N1,N 2-di-p-anisyl-formamidine (HDAniF) ligands and the bridging acetate ligands. The molecule is one of the few examples of a crystallographically characterized axial bis-adduct of a (Ru2\}4+ complex with two N-donor ligands.",

author = "Panagiotis Angaridis and \{Albert Cotton\}, F. and Murillo, \{Carlos A.\} and Wang, \{Xiao Ping\}",

year = "2005",

month = feb,

doi = "10.1107/S0108270104032494",

language = "English",

volume = "61",

pages = "m109--m111",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

number = "2",

}

Angaridis, P, Albert Cotton, F, Murillo, CA & Wang, XP 2005, 'Tetra-μ-acetato-κ⁸O:O′-bis[(N¹,N ²-di-p-anisylformamidine-κN²)ruthenium(II)]-(Ru - Ru): An example of an axial bis-adduct of {Ru₂}⁴⁺ tetracarboxylate with N-donor ligands', Acta Crystallographica Section C: Crystal Structure Communications, vol. 61, no. 2, pp. m109-m111. https://doi.org/10.1107/S0108270104032494

Tetra-μ-acetato-κ⁸O:O′-bis[(N¹,N ²-di-p-anisylformamidine-κN²)ruthenium(II)]-(Ru - Ru): An example of an axial bis-adduct of {Ru₂}⁴⁺ tetracarboxylate with N-donor ligands. / Angaridis, Panagiotis; Albert Cotton, F.; Murillo, Carlos A. et al.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 61, No. 2, 02.2005, p. m109-m111.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Tetra-μ-acetato-κ8O:O′-bis[(N1,N 2-di-p-anisylformamidine-κN2)ruthenium(II)]-(Ru - Ru)

T2 - An example of an axial bis-adduct of {Ru2}4+ tetracarboxylate with N-donor ligands

AU - Angaridis, Panagiotis

AU - Albert Cotton, F.

AU - Murillo, Carlos A.

AU - Wang, Xiao Ping

PY - 2005/2

Y1 - 2005/2

N2 - The title compound, [Ru2(C2H3O 2)4(C15H16N2O 2)2], lies on a crystallographic inversion center and exhibits an Ru-Ru bond length of 2.2847 (8) Å. There are weak intramolecular hydrogen-bonding interactions between the N1,N 2-di-p-anisyl-formamidine (HDAniF) ligands and the bridging acetate ligands. The molecule is one of the few examples of a crystallographically characterized axial bis-adduct of a (Ru2}4+ complex with two N-donor ligands.

AB - The title compound, [Ru2(C2H3O 2)4(C15H16N2O 2)2], lies on a crystallographic inversion center and exhibits an Ru-Ru bond length of 2.2847 (8) Å. There are weak intramolecular hydrogen-bonding interactions between the N1,N 2-di-p-anisyl-formamidine (HDAniF) ligands and the bridging acetate ligands. The molecule is one of the few examples of a crystallographically characterized axial bis-adduct of a (Ru2}4+ complex with two N-donor ligands.

UR - https://www.scopus.com/pages/publications/30944456558

U2 - 10.1107/S0108270104032494

DO - 10.1107/S0108270104032494

M3 - Article

AN - SCOPUS:30944456558

SN - 0108-2701

VL - 61

SP - m109-m111

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

Tetra-μ-acetato-κ⁸O:O′-bis[(N¹,N ²-di-p-anisylformamidine-κN²)ruthenium(II)]-(Ru - Ru): An example of an axial bis-adduct of {Ru₂}⁴⁺ tetracarboxylate with N-donor ligands

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