Template-free synthesis of hierarchical porous metal-organic frameworks

Yanfeng Yue; Zhen An Qiao; Pasquale F. Fulvio; Andrew J. Binder; Chengcheng Tian; Jihua Chen; Kimberly M. Nelson; Xiang Zhu; Sheng Dai

doi:10.1021/ja402694f

Template-free synthesis of hierarchical porous metal-organic frameworks

Yanfeng Yue, Zhen An Qiao, Pasquale F. Fulvio, Andrew J. Binder, Chengcheng Tian, Jihua Chen, Kimberly M. Nelson, Xiang Zhu, Sheng Dai

Research output: Contribution to journal › Article › peer-review

198 Scopus citations

Abstract

A template-free synthesis of a hierarchical microporous-mesoporous metal-organic framework (MOF) of zinc(II) 2,5-dihydroxy-1,4-benzenedicarboxylate (Zn-MOF-74) is reported. The surface morphology and porosity of the bimodal materials can be modified by etching the pore walls with various synthesis solvents for different reaction times. This template-free strategy enables the preparation of stable frameworks with mesopores exceeding 15 nm, which was previously unattained in the synthesis of MOFs by the ligand-extension method.

Original language	English
Pages (from-to)	9572-9575
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	26
DOIs	https://doi.org/10.1021/ja402694f
State	Published - Jul 3 2013

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10.1021/ja402694f

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title = "Template-free synthesis of hierarchical porous metal-organic frameworks",

abstract = "A template-free synthesis of a hierarchical microporous-mesoporous metal-organic framework (MOF) of zinc(II) 2,5-dihydroxy-1,4-benzenedicarboxylate (Zn-MOF-74) is reported. The surface morphology and porosity of the bimodal materials can be modified by etching the pore walls with various synthesis solvents for different reaction times. This template-free strategy enables the preparation of stable frameworks with mesopores exceeding 15 nm, which was previously unattained in the synthesis of MOFs by the ligand-extension method.",

author = "Yanfeng Yue and Qiao, {Zhen An} and Fulvio, {Pasquale F.} and Binder, {Andrew J.} and Chengcheng Tian and Jihua Chen and Nelson, {Kimberly M.} and Xiang Zhu and Sheng Dai",

year = "2013",

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doi = "10.1021/ja402694f",

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T1 - Template-free synthesis of hierarchical porous metal-organic frameworks

AU - Yue, Yanfeng

AU - Qiao, Zhen An

AU - Fulvio, Pasquale F.

AU - Binder, Andrew J.

AU - Tian, Chengcheng

AU - Chen, Jihua

AU - Nelson, Kimberly M.

AU - Zhu, Xiang

AU - Dai, Sheng

PY - 2013/7/3

Y1 - 2013/7/3

N2 - A template-free synthesis of a hierarchical microporous-mesoporous metal-organic framework (MOF) of zinc(II) 2,5-dihydroxy-1,4-benzenedicarboxylate (Zn-MOF-74) is reported. The surface morphology and porosity of the bimodal materials can be modified by etching the pore walls with various synthesis solvents for different reaction times. This template-free strategy enables the preparation of stable frameworks with mesopores exceeding 15 nm, which was previously unattained in the synthesis of MOFs by the ligand-extension method.

AB - A template-free synthesis of a hierarchical microporous-mesoporous metal-organic framework (MOF) of zinc(II) 2,5-dihydroxy-1,4-benzenedicarboxylate (Zn-MOF-74) is reported. The surface morphology and porosity of the bimodal materials can be modified by etching the pore walls with various synthesis solvents for different reaction times. This template-free strategy enables the preparation of stable frameworks with mesopores exceeding 15 nm, which was previously unattained in the synthesis of MOFs by the ligand-extension method.

UR - http://www.scopus.com/inward/record.url?scp=84879770736&partnerID=8YFLogxK

U2 - 10.1021/ja402694f

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M3 - Article

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VL - 135

SP - 9572

EP - 9575

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 26

ER -

Template-free synthesis of hierarchical porous metal-organic frameworks

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