Abstract
A tBu3P-coordinated 2-phenylaniline-based palladacycle complex was demonstrated to be an efficient precatalyst for Pd-catalyzed coupling reactions of aryl halides with polyfluoroarenes that operates through a C-H activation strategy. The ready accessibility and ease of handling of the complex and the high yields of the reaction makes this palladacycle complex an attractive precatalyst for the cross-coupling reaction of aryl halides with polyfluoroarenes. A tBu3P-coordinated 2-phenylaniline-based palladacycle complex was found to be an efficient precatalyst for Pd-catalyzed coupling reactions of aryl halides with polyfluoroarenes that operates through a C-H activation strategy, with good to excellent product yields being observed.
Original language | English |
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Pages (from-to) | 1327-1332 |
Number of pages | 6 |
Journal | European Journal of Organic Chemistry |
Volume | 2014 |
Issue number | 6 |
DOIs | |
State | Published - Feb 2014 |
Externally published | Yes |
Keywords
- C-C coupling
- C-H activation
- Fluorine
- Metallacycles
- Palladium
- Synthetic methods