TBu3P-coordinated 2-phenylaniline-based palladacycle complexes as precatalyst for Pd-catalyzed coupling reactions of aryl halides with polyfluoroarenes by a C-H activation strategy

Hong Hai Zhang, Jie Dong, Qiao Sheng Hu

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

A tBu3P-coordinated 2-phenylaniline-based palladacycle complex was demonstrated to be an efficient precatalyst for Pd-catalyzed coupling reactions of aryl halides with polyfluoroarenes that operates through a C-H activation strategy. The ready accessibility and ease of handling of the complex and the high yields of the reaction makes this palladacycle complex an attractive precatalyst for the cross-coupling reaction of aryl halides with polyfluoroarenes. A tBu3P-coordinated 2-phenylaniline-based palladacycle complex was found to be an efficient precatalyst for Pd-catalyzed coupling reactions of aryl halides with polyfluoroarenes that operates through a C-H activation strategy, with good to excellent product yields being observed.

Original languageEnglish
Pages (from-to)1327-1332
Number of pages6
JournalEuropean Journal of Organic Chemistry
Volume2014
Issue number6
DOIs
StatePublished - Feb 2014
Externally publishedYes

Keywords

  • C-C coupling
  • C-H activation
  • Fluorine
  • Metallacycles
  • Palladium
  • Synthetic methods

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