Tapered Bottlebrush Polymers: Cone-Shaped Nanostructures by Sequential Addition of Macromonomers

Scott C. Radzinski; Jeffrey C. Foster; Samantha J. Scannelli; Jeffrey R. Weaver; Kyle J. Arrington; John B. Matson

doi:10.1021/acsmacrolett.7b00724

Tapered Bottlebrush Polymers: Cone-Shaped Nanostructures by Sequential Addition of Macromonomers

Scott C. Radzinski
, Jeffrey C. Foster
, Samantha J. Scannelli
, Jeffrey R. Weaver
, Kyle J. Arrington
, John B. Matson

Research output: Contribution to journal › Article › peer-review

79 Scopus citations

Abstract

Tapered (cone-shaped) bottlebrush polymers were synthesized for the first time by ring-opening metathesis polymerization (ROMP) using a sequential-addition of macromonomers (SAM) strategy. Polystyrene macromonomers with molecular weights that increased from 1 to 10 kg mol^-1 were polymerized in sequence to high conversion, yielding tapered bottlebrush polymers that could be visualized by atomic force microscopy (AFM).

Original language	English
Pages (from-to)	1175-1179
Number of pages	5
Journal	ACS Macro Letters
Volume	6
Issue number	10
DOIs	https://doi.org/10.1021/acsmacrolett.7b00724
State	Published - Oct 17 2017
Externally published	Yes

Funding

This work was supported by the Army Research Office (W911NF-14-1-0322) and the American Chemical Society Petroleum Research Fund (54884-DNI7). Notes The authors declare no competing financial interest.

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10.1021/acsmacrolett.7b00724

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title = "Tapered Bottlebrush Polymers: Cone-Shaped Nanostructures by Sequential Addition of Macromonomers",

abstract = "Tapered (cone-shaped) bottlebrush polymers were synthesized for the first time by ring-opening metathesis polymerization (ROMP) using a sequential-addition of macromonomers (SAM) strategy. Polystyrene macromonomers with molecular weights that increased from 1 to 10 kg mol-1 were polymerized in sequence to high conversion, yielding tapered bottlebrush polymers that could be visualized by atomic force microscopy (AFM).",

author = "Radzinski, \{Scott C.\} and Foster, \{Jeffrey C.\} and Scannelli, \{Samantha J.\} and Weaver, \{Jeffrey R.\} and Arrington, \{Kyle J.\} and Matson, \{John B.\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

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doi = "10.1021/acsmacrolett.7b00724",

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AU - Radzinski, Scott C.

AU - Foster, Jeffrey C.

AU - Scannelli, Samantha J.

AU - Weaver, Jeffrey R.

AU - Arrington, Kyle J.

AU - Matson, John B.

PY - 2017/10/17

Y1 - 2017/10/17

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AB - Tapered (cone-shaped) bottlebrush polymers were synthesized for the first time by ring-opening metathesis polymerization (ROMP) using a sequential-addition of macromonomers (SAM) strategy. Polystyrene macromonomers with molecular weights that increased from 1 to 10 kg mol-1 were polymerized in sequence to high conversion, yielding tapered bottlebrush polymers that could be visualized by atomic force microscopy (AFM).

UR - https://www.scopus.com/pages/publications/85031706116

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Tapered Bottlebrush Polymers: Cone-Shaped Nanostructures by Sequential Addition of Macromonomers

Abstract

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