Synthesis, structure and physical properties of a new organic metal, (BEDO-TTF)4[C4N6]·H2O

Brian H. Ward; Garrett E. Granroth; James B. Walden; Khalil A. Abboud; Mark W. Meisel; Paul G. Rasmussen; Daniel R. Talham

doi:10.1039/a708481a

Synthesis, structure and physical properties of a new organic metal, (BEDO-TTF)₄[C₄N₆]·H₂O

Brian H. Ward
, Garrett E. Granroth
, James B. Walden
, Khalil A. Abboud
, Mark W. Meisel
, Paul G. Rasmussen
, Daniel R. Talham

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A new organic metal based on the π-donor bis(ethylenedioxy)tetrathiafulvalene, (BEDO-TTF)₄[C₄N₆]·H₂O, has been isolated as the N,N′,N″-tricyanoguanidinate monohydrate salt. The crystal structure indicates strong two-dimensional (2D) behavior in the BEDO-TTF donor layer demonstrated by the close intermolecular C-H⋯O, S⋯S, and S⋯O contacts. The N,N′,N″-tricyanoguanidinate dianions are puckered and form dimers through hydrogen bonding with two water molecules, resulting in an infinite sheet of dianions that complement the 2D nature of the BEDO-TTF donor layers. Four-probe resistance, tunnel diode oscillator, and EPR measurements indicate metallic behavior down to 8 K where a metal-semiconductor transition occurs. (BEDO-TTF)₄[C₄N₆]·H₂O crystallizes in the P1 space group with a = 11.9628(2), b = 14.1016(2), c = 17.0830(2) Å, α = 81.27(1), β = 70.21(1), γ =77.04(1)°, V =2633.39(7) Å³, Z = 2.

Original language	English
Pages (from-to)	1373-1378
Number of pages	6
Journal	Journal of Materials Chemistry
Volume	8
Issue number	6
DOIs	https://doi.org/10.1039/a708481a
State	Published - Jun 1998
Externally published	Yes

Access to Document

10.1039/a708481a

Cite this

@article{cb1a21ebbd614fd4a809e73e589f05bb,

title = "Synthesis, structure and physical properties of a new organic metal, (BEDO-TTF)4[C4N6]·H2O",

abstract = "A new organic metal based on the π-donor bis(ethylenedioxy)tetrathiafulvalene, (BEDO-TTF)4[C4N6]·H2O, has been isolated as the N,N′,N″-tricyanoguanidinate monohydrate salt. The crystal structure indicates strong two-dimensional (2D) behavior in the BEDO-TTF donor layer demonstrated by the close intermolecular C-H⋯O, S⋯S, and S⋯O contacts. The N,N′,N″-tricyanoguanidinate dianions are puckered and form dimers through hydrogen bonding with two water molecules, resulting in an infinite sheet of dianions that complement the 2D nature of the BEDO-TTF donor layers. Four-probe resistance, tunnel diode oscillator, and EPR measurements indicate metallic behavior down to 8 K where a metal-semiconductor transition occurs. (BEDO-TTF)4[C4N6]·H2O crystallizes in the P1 space group with a = 11.9628(2), b = 14.1016(2), c = 17.0830(2) {\AA}, α = 81.27(1), β = 70.21(1), γ =77.04(1)°, V =2633.39(7) {\AA}3, Z = 2.",

author = "Ward, \{Brian H.\} and Granroth, \{Garrett E.\} and Walden, \{James B.\} and Abboud, \{Khalil A.\} and Meisel, \{Mark W.\} and Rasmussen, \{Paul G.\} and Talham, \{Daniel R.\}",

year = "1998",

month = jun,

doi = "10.1039/a708481a",

language = "English",

volume = "8",

pages = "1373--1378",

journal = "Journal of Materials Chemistry",

issn = "0959-9428",

number = "6",

}

TY - JOUR

T1 - Synthesis, structure and physical properties of a new organic metal, (BEDO-TTF)4[C4N6]·H2O

AU - Ward, Brian H.

AU - Granroth, Garrett E.

AU - Walden, James B.

AU - Abboud, Khalil A.

AU - Meisel, Mark W.

AU - Rasmussen, Paul G.

AU - Talham, Daniel R.

PY - 1998/6

Y1 - 1998/6

N2 - A new organic metal based on the π-donor bis(ethylenedioxy)tetrathiafulvalene, (BEDO-TTF)4[C4N6]·H2O, has been isolated as the N,N′,N″-tricyanoguanidinate monohydrate salt. The crystal structure indicates strong two-dimensional (2D) behavior in the BEDO-TTF donor layer demonstrated by the close intermolecular C-H⋯O, S⋯S, and S⋯O contacts. The N,N′,N″-tricyanoguanidinate dianions are puckered and form dimers through hydrogen bonding with two water molecules, resulting in an infinite sheet of dianions that complement the 2D nature of the BEDO-TTF donor layers. Four-probe resistance, tunnel diode oscillator, and EPR measurements indicate metallic behavior down to 8 K where a metal-semiconductor transition occurs. (BEDO-TTF)4[C4N6]·H2O crystallizes in the P1 space group with a = 11.9628(2), b = 14.1016(2), c = 17.0830(2) Å, α = 81.27(1), β = 70.21(1), γ =77.04(1)°, V =2633.39(7) Å3, Z = 2.

AB - A new organic metal based on the π-donor bis(ethylenedioxy)tetrathiafulvalene, (BEDO-TTF)4[C4N6]·H2O, has been isolated as the N,N′,N″-tricyanoguanidinate monohydrate salt. The crystal structure indicates strong two-dimensional (2D) behavior in the BEDO-TTF donor layer demonstrated by the close intermolecular C-H⋯O, S⋯S, and S⋯O contacts. The N,N′,N″-tricyanoguanidinate dianions are puckered and form dimers through hydrogen bonding with two water molecules, resulting in an infinite sheet of dianions that complement the 2D nature of the BEDO-TTF donor layers. Four-probe resistance, tunnel diode oscillator, and EPR measurements indicate metallic behavior down to 8 K where a metal-semiconductor transition occurs. (BEDO-TTF)4[C4N6]·H2O crystallizes in the P1 space group with a = 11.9628(2), b = 14.1016(2), c = 17.0830(2) Å, α = 81.27(1), β = 70.21(1), γ =77.04(1)°, V =2633.39(7) Å3, Z = 2.

UR - https://www.scopus.com/pages/publications/0000903971

U2 - 10.1039/a708481a

DO - 10.1039/a708481a

M3 - Article

AN - SCOPUS:0000903971

SN - 0959-9428

VL - 8

SP - 1373

EP - 1378

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

IS - 6

ER -

Synthesis, structure and physical properties of a new organic metal, (BEDO-TTF)₄[C₄N₆]·H₂O

Abstract

Access to Document

Other files and links

Fingerprint

Cite this