Synthesis, structural characterization, and hydrogen bonds of Co9(OH)14[SO4]2

Hamdi Ben Yahia; Masahiro Shikano; Ilias Belharouak

doi:10.1515/znb-2017-0046

Synthesis, structural characterization, and hydrogen bonds of Co₉(OH)₁₄[SO₄]₂

Hamdi Ben Yahia, Masahiro Shikano, Ilias Belharouak

Research output: Contribution to journal › Article › peer-review

Abstract

The new compound Co₉(OH)₁₄[SO₄]₂ was synthesized using a hydrothermal method from LiF, Na₂SO₃, and Co(CH₃COO) ₂4H₂O in a molar ratio of 1:1:1 in the presence of atmospheric oxygen. Its crystal structure was determined from single crystal X-ray diffraction data. Co₉(OH)₁₄[SO₄]₂ crystallizes in the triclinic system, space group P1 with a =7.693(2) Å, b =8.318(2) Å, c =8.351(2) Å, α =82.375(5)°, Beta; =77.832(4)°, γ = 68.395(4)°, V = 484.8(2) Å3, and Z = 2. Its structure is composed of cobalt-containing sheets interconnected by SO4 tetrahedra. Bent and symmetrically trifurcated hydrogen bonds have been observed. Furthermore, structural similarities with hydrozincite and brucite minerals have been noticed.

Original language	English
Pages (from-to)	505-510
Number of pages	6
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	72
Issue number	7
DOIs	https://doi.org/10.1515/znb-2017-0046
State	Published - 2017
Externally published	Yes

Keywords

Batteries
Crystal structure
Hydrogen bonds
Hydrothermal synthesis
Polyanions
X-ray structure determination.

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@article{27a886e952db4edfbfc1e339b290f4b4,

title = "Synthesis, structural characterization, and hydrogen bonds of Co9(OH)14[SO4]2",

abstract = "The new compound Co9(OH)14[SO4]2 was synthesized using a hydrothermal method from LiF, Na2SO3, and Co(CH3COO) 24H2O in a molar ratio of 1:1:1 in the presence of atmospheric oxygen. Its crystal structure was determined from single crystal X-ray diffraction data. Co9(OH)14[SO4]2 crystallizes in the triclinic system, space group P1 with a =7.693(2) {\AA}, b =8.318(2) {\AA}, c =8.351(2) {\AA}, α =82.375(5)°, Beta; =77.832(4)°, γ = 68.395(4)°, V = 484.8(2) {\AA}3, and Z = 2. Its structure is composed of cobalt-containing sheets interconnected by SO4 tetrahedra. Bent and symmetrically trifurcated hydrogen bonds have been observed. Furthermore, structural similarities with hydrozincite and brucite minerals have been noticed.",

keywords = "Batteries, Crystal structure, Hydrogen bonds, Hydrothermal synthesis, Polyanions, X-ray structure determination.",

author = "Yahia, {Hamdi Ben} and Masahiro Shikano and Ilias Belharouak",

year = "2017",

doi = "10.1515/znb-2017-0046",

language = "English",

volume = "72",

pages = "505--510",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "De Gruyter",

number = "7",

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TY - JOUR

T1 - Synthesis, structural characterization, and hydrogen bonds of Co9(OH)14[SO4]2

AU - Yahia, Hamdi Ben

AU - Shikano, Masahiro

AU - Belharouak, Ilias

PY - 2017

Y1 - 2017

N2 - The new compound Co9(OH)14[SO4]2 was synthesized using a hydrothermal method from LiF, Na2SO3, and Co(CH3COO) 24H2O in a molar ratio of 1:1:1 in the presence of atmospheric oxygen. Its crystal structure was determined from single crystal X-ray diffraction data. Co9(OH)14[SO4]2 crystallizes in the triclinic system, space group P1 with a =7.693(2) Å, b =8.318(2) Å, c =8.351(2) Å, α =82.375(5)°, Beta; =77.832(4)°, γ = 68.395(4)°, V = 484.8(2) Å3, and Z = 2. Its structure is composed of cobalt-containing sheets interconnected by SO4 tetrahedra. Bent and symmetrically trifurcated hydrogen bonds have been observed. Furthermore, structural similarities with hydrozincite and brucite minerals have been noticed.

AB - The new compound Co9(OH)14[SO4]2 was synthesized using a hydrothermal method from LiF, Na2SO3, and Co(CH3COO) 24H2O in a molar ratio of 1:1:1 in the presence of atmospheric oxygen. Its crystal structure was determined from single crystal X-ray diffraction data. Co9(OH)14[SO4]2 crystallizes in the triclinic system, space group P1 with a =7.693(2) Å, b =8.318(2) Å, c =8.351(2) Å, α =82.375(5)°, Beta; =77.832(4)°, γ = 68.395(4)°, V = 484.8(2) Å3, and Z = 2. Its structure is composed of cobalt-containing sheets interconnected by SO4 tetrahedra. Bent and symmetrically trifurcated hydrogen bonds have been observed. Furthermore, structural similarities with hydrozincite and brucite minerals have been noticed.

KW - Batteries

KW - Crystal structure

KW - Hydrogen bonds

KW - Hydrothermal synthesis

KW - Polyanions

KW - X-ray structure determination.

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U2 - 10.1515/znb-2017-0046

DO - 10.1515/znb-2017-0046

M3 - Article

AN - SCOPUS:85025440111

SN - 0932-0776

VL - 72

SP - 505

EP - 510

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 7

ER -

Synthesis, structural characterization, and hydrogen bonds of Co₉(OH)₁₄[SO₄]₂

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Keywords

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