Synthesis of metalloporphyrin-based conjugated microporous polymer spheres directed by bipyridine-type ligands

Guipeng Ji; Zhenzhen Yang; Yanfei Zhao; Hongye Zhang; Bo Yu; Jilei Xu; Huanjun Xu; Zhimin Liu

doi:10.1039/c5cc00609k

Synthesis of metalloporphyrin-based conjugated microporous polymer spheres directed by bipyridine-type ligands

Guipeng Ji
, Zhenzhen Yang
, Yanfei Zhao
, Hongye Zhang
, Bo Yu
, Jilei Xu
, Huanjun Xu
, Zhimin Liu

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Zinc porphyrin (TP-Zn)-based conjugated microporous polymer (Zn-CMP) spheres were obtained via Sonagashira-Hagihara cross coupling reactions between 5,10,15,20-tetrakis(4-ethynylphenyl)porphyrin-Zn(II) and brominated monomers directed by bidentate bipyridine (BP)-type ligands for the first time, and the sphere diameters could be adjusted from 320 to 740 nm. The coordination between BP and TP-Zn was proved to be the key to forming spheres.

Original language	English
Pages (from-to)	7352-7355
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	34
DOIs	https://doi.org/10.1039/c5cc00609k
State	Published - Apr 30 2015
Externally published	Yes

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title = "Synthesis of metalloporphyrin-based conjugated microporous polymer spheres directed by bipyridine-type ligands",

abstract = "Zinc porphyrin (TP-Zn)-based conjugated microporous polymer (Zn-CMP) spheres were obtained via Sonagashira-Hagihara cross coupling reactions between 5,10,15,20-tetrakis(4-ethynylphenyl)porphyrin-Zn(II) and brominated monomers directed by bidentate bipyridine (BP)-type ligands for the first time, and the sphere diameters could be adjusted from 320 to 740 nm. The coordination between BP and TP-Zn was proved to be the key to forming spheres.",

author = "Guipeng Ji and Zhenzhen Yang and Yanfei Zhao and Hongye Zhang and Bo Yu and Jilei Xu and Huanjun Xu and Zhimin Liu",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = apr,

day = "30",

doi = "10.1039/c5cc00609k",

language = "English",

volume = "51",

pages = "7352--7355",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Synthesis of metalloporphyrin-based conjugated microporous polymer spheres directed by bipyridine-type ligands

AU - Ji, Guipeng

AU - Yang, Zhenzhen

AU - Zhao, Yanfei

AU - Zhang, Hongye

AU - Yu, Bo

AU - Xu, Jilei

AU - Xu, Huanjun

AU - Liu, Zhimin

PY - 2015/4/30

Y1 - 2015/4/30

N2 - Zinc porphyrin (TP-Zn)-based conjugated microporous polymer (Zn-CMP) spheres were obtained via Sonagashira-Hagihara cross coupling reactions between 5,10,15,20-tetrakis(4-ethynylphenyl)porphyrin-Zn(II) and brominated monomers directed by bidentate bipyridine (BP)-type ligands for the first time, and the sphere diameters could be adjusted from 320 to 740 nm. The coordination between BP and TP-Zn was proved to be the key to forming spheres.

AB - Zinc porphyrin (TP-Zn)-based conjugated microporous polymer (Zn-CMP) spheres were obtained via Sonagashira-Hagihara cross coupling reactions between 5,10,15,20-tetrakis(4-ethynylphenyl)porphyrin-Zn(II) and brominated monomers directed by bidentate bipyridine (BP)-type ligands for the first time, and the sphere diameters could be adjusted from 320 to 740 nm. The coordination between BP and TP-Zn was proved to be the key to forming spheres.

UR - https://www.scopus.com/pages/publications/84927927381

U2 - 10.1039/c5cc00609k

DO - 10.1039/c5cc00609k

M3 - Article

AN - SCOPUS:84927927381

SN - 1359-7345

VL - 51

SP - 7352

EP - 7355

JO - Chemical Communications

JF - Chemical Communications

IS - 34

ER -

Synthesis of metalloporphyrin-based conjugated microporous polymer spheres directed by bipyridine-type ligands

Abstract

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