Synthesis of Lithio-F-adamantanes: The First Documented 19F NMR Spectrum of a Perfluoroalkyllithium and the Rearrangement of 2-Lithio-F-adamantane to 1-Lithio-F-adamantane

James L. Adcock; Huimin Luo

doi:10.1021/jo00060a007

Synthesis of Lithio-F-adamantanes: The First Documented ¹⁹F NMR Spectrum of a Perfluoroalkyllithium and the Rearrangement of 2-Lithio-F-adamantane to 1-Lithio-F-adamantane

James L. Adcock
, Huimin Luo

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The synthesis, ¹⁹F-NMR, and reactions of a very stable diamondoid perfluoroalkyllithium, 1-lithio-F-adamantane, and the observation of an unusual rearrangement of 2-lithio-F-adamantane to 1-lithio-F-adamantane are reported.

Original language	English
Pages (from-to)	1999-2000
Number of pages	2
Journal	Journal of Organic Chemistry
Volume	58
Issue number	8
DOIs	https://doi.org/10.1021/jo00060a007
State	Published - 1993
Externally published	Yes

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@article{629869e554754e9a80fcc7a8c41ab2d5,

title = "Synthesis of Lithio-F-adamantanes: The First Documented 19F NMR Spectrum of a Perfluoroalkyllithium and the Rearrangement of 2-Lithio-F-adamantane to 1-Lithio-F-adamantane",

abstract = "The synthesis, 19F-NMR, and reactions of a very stable diamondoid perfluoroalkyllithium, 1-lithio-F-adamantane, and the observation of an unusual rearrangement of 2-lithio-F-adamantane to 1-lithio-F-adamantane are reported.",

author = "Adcock, \{James L.\} and Huimin Luo",

year = "1993",

doi = "10.1021/jo00060a007",

language = "English",

volume = "58",

pages = "1999--2000",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - Synthesis of Lithio-F-adamantanes

T2 - The First Documented 19F NMR Spectrum of a Perfluoroalkyllithium and the Rearrangement of 2-Lithio-F-adamantane to 1-Lithio-F-adamantane

AU - Adcock, James L.

AU - Luo, Huimin

PY - 1993

Y1 - 1993

N2 - The synthesis, 19F-NMR, and reactions of a very stable diamondoid perfluoroalkyllithium, 1-lithio-F-adamantane, and the observation of an unusual rearrangement of 2-lithio-F-adamantane to 1-lithio-F-adamantane are reported.

AB - The synthesis, 19F-NMR, and reactions of a very stable diamondoid perfluoroalkyllithium, 1-lithio-F-adamantane, and the observation of an unusual rearrangement of 2-lithio-F-adamantane to 1-lithio-F-adamantane are reported.

UR - https://www.scopus.com/pages/publications/33746348984

U2 - 10.1021/jo00060a007

DO - 10.1021/jo00060a007

M3 - Article

AN - SCOPUS:33746348984

SN - 0022-3263

VL - 58

SP - 1999

EP - 2000

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 8

ER -

Synthesis of Lithio-F-adamantanes: The First Documented ¹⁹F NMR Spectrum of a Perfluoroalkyllithium and the Rearrangement of 2-Lithio-F-adamantane to 1-Lithio-F-adamantane

Abstract

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