Synthesis of a bifunctional initiator for controlled Kumada catalyst-transfer polycondensation/nitroxide-mediated polymerization and preparation of poly(3-hexylthiophene)-polystyrene block copolymer therefrom

Elisabeth Kaul; Volodymyr Senkovskyy; Roman Tkachov; Vera Bocharova; Hartmut Komber; Manfred Stamm; Anton Kiriy

doi:10.1021/ma902354j

Synthesis of a bifunctional initiator for controlled Kumada catalyst-transfer polycondensation/nitroxide-mediated polymerization and preparation of poly(3-hexylthiophene)-polystyrene block copolymer therefrom

Elisabeth Kaul, Volodymyr Senkovskyy, Roman Tkachov, Vera Bocharova, Hartmut Komber, Manfred Stamm, Anton Kiriy

Research output: Contribution to journal › Article › peer-review

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Abstract

Herein, we present a new approach to synthesize rod-coil block copolymers via consecutive Kumada catalyst-transfer polycondensation (KCTP) and nitroxide-mediated free radical polymerization (NMP) performed from a bifunctional initiator, TIPNO-Ph-Ni(dppp)-Br (TIPNO = 2,2,5-trimethyl-4phenyl-3- azahexane-3-nitroxide; dppp = propane-l,3-diylbis(diphenylphosphane). The utility of the method was exemplified in a preparation of a model block copolymer, poly(3-hexylthiophene)-block-polystyrene (P3HT-b-PS) with a relatively narrow molecular weight distribution of 1.33. Synthesis of the bifunctional initiator was accomplished by a reaction of diethylbipyridylnickel with a readily accessible precursor, TIPNO-Ph-Br, followed by in situ replacement of the bipyridyl ligand onto bidentate phosphorus one

Original language	English
Pages (from-to)	77-81
Number of pages	5
Journal	Macromolecules
Volume	43
Issue number	1
DOIs	https://doi.org/10.1021/ma902354j
State	Published - Jan 12 2010
Externally published	Yes

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Kaul, E., Senkovskyy, V., Tkachov, R., Bocharova, V., Komber, H., Stamm, M., & Kiriy, A. (2010). Synthesis of a bifunctional initiator for controlled Kumada catalyst-transfer polycondensation/nitroxide-mediated polymerization and preparation of poly(3-hexylthiophene)-polystyrene block copolymer therefrom. Macromolecules, 43(1), 77-81. https://doi.org/10.1021/ma902354j

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title = "Synthesis of a bifunctional initiator for controlled Kumada catalyst-transfer polycondensation/nitroxide-mediated polymerization and preparation of poly(3-hexylthiophene)-polystyrene block copolymer therefrom",

abstract = "Herein, we present a new approach to synthesize rod-coil block copolymers via consecutive Kumada catalyst-transfer polycondensation (KCTP) and nitroxide-mediated free radical polymerization (NMP) performed from a bifunctional initiator, TIPNO-Ph-Ni(dppp)-Br (TIPNO = 2,2,5-trimethyl-4phenyl-3- azahexane-3-nitroxide; dppp = propane-l,3-diylbis(diphenylphosphane). The utility of the method was exemplified in a preparation of a model block copolymer, poly(3-hexylthiophene)-block-polystyrene (P3HT-b-PS) with a relatively narrow molecular weight distribution of 1.33. Synthesis of the bifunctional initiator was accomplished by a reaction of diethylbipyridylnickel with a readily accessible precursor, TIPNO-Ph-Br, followed by in situ replacement of the bipyridyl ligand onto bidentate phosphorus one",

author = "Elisabeth Kaul and Volodymyr Senkovskyy and Roman Tkachov and Vera Bocharova and Hartmut Komber and Manfred Stamm and Anton Kiriy",

year = "2010",

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Kaul, E, Senkovskyy, V, Tkachov, R, Bocharova, V, Komber, H, Stamm, M & Kiriy, A 2010, 'Synthesis of a bifunctional initiator for controlled Kumada catalyst-transfer polycondensation/nitroxide-mediated polymerization and preparation of poly(3-hexylthiophene)-polystyrene block copolymer therefrom', Macromolecules, vol. 43, no. 1, pp. 77-81. https://doi.org/10.1021/ma902354j

Synthesis of a bifunctional initiator for controlled Kumada catalyst-transfer polycondensation/nitroxide-mediated polymerization and preparation of poly(3-hexylthiophene)-polystyrene block copolymer therefrom. / Kaul, Elisabeth; Senkovskyy, Volodymyr; Tkachov, Roman et al.
In: Macromolecules, Vol. 43, No. 1, 12.01.2010, p. 77-81.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of a bifunctional initiator for controlled Kumada catalyst-transfer polycondensation/nitroxide-mediated polymerization and preparation of poly(3-hexylthiophene)-polystyrene block copolymer therefrom

AU - Kaul, Elisabeth

AU - Senkovskyy, Volodymyr

AU - Tkachov, Roman

AU - Bocharova, Vera

AU - Komber, Hartmut

AU - Stamm, Manfred

AU - Kiriy, Anton

PY - 2010/1/12

Y1 - 2010/1/12

N2 - Herein, we present a new approach to synthesize rod-coil block copolymers via consecutive Kumada catalyst-transfer polycondensation (KCTP) and nitroxide-mediated free radical polymerization (NMP) performed from a bifunctional initiator, TIPNO-Ph-Ni(dppp)-Br (TIPNO = 2,2,5-trimethyl-4phenyl-3- azahexane-3-nitroxide; dppp = propane-l,3-diylbis(diphenylphosphane). The utility of the method was exemplified in a preparation of a model block copolymer, poly(3-hexylthiophene)-block-polystyrene (P3HT-b-PS) with a relatively narrow molecular weight distribution of 1.33. Synthesis of the bifunctional initiator was accomplished by a reaction of diethylbipyridylnickel with a readily accessible precursor, TIPNO-Ph-Br, followed by in situ replacement of the bipyridyl ligand onto bidentate phosphorus one

AB - Herein, we present a new approach to synthesize rod-coil block copolymers via consecutive Kumada catalyst-transfer polycondensation (KCTP) and nitroxide-mediated free radical polymerization (NMP) performed from a bifunctional initiator, TIPNO-Ph-Ni(dppp)-Br (TIPNO = 2,2,5-trimethyl-4phenyl-3- azahexane-3-nitroxide; dppp = propane-l,3-diylbis(diphenylphosphane). The utility of the method was exemplified in a preparation of a model block copolymer, poly(3-hexylthiophene)-block-polystyrene (P3HT-b-PS) with a relatively narrow molecular weight distribution of 1.33. Synthesis of the bifunctional initiator was accomplished by a reaction of diethylbipyridylnickel with a readily accessible precursor, TIPNO-Ph-Br, followed by in situ replacement of the bipyridyl ligand onto bidentate phosphorus one

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DO - 10.1021/ma902354j

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SN - 0024-9297

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JO - Macromolecules

JF - Macromolecules

IS - 1

ER -

Synthesis of a bifunctional initiator for controlled Kumada catalyst-transfer polycondensation/nitroxide-mediated polymerization and preparation of poly(3-hexylthiophene)-polystyrene block copolymer therefrom

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