Synthesis, crystal structure and vibrational spectra of a new diammonium zinc(II) dihydrogendiphosphate dihydrate, (NH4)2Zn(H 2P2O7)2·2H2O

Rachid Essehli; Mohammed Lachkar; Ingrid Svoboda; Hartmut Fuess; Brahim El Bali

doi:10.1107/S1600536805004642

Synthesis, crystal structure and vibrational spectra of a new diammonium zinc(II) dihydrogendiphosphate dihydrate, (NH₄)₂Zn(H ₂P₂O₇)₂·2H₂O

Rachid Essehli
, Mohammed Lachkar
, Ingrid Svoboda
, Hartmut Fuess
, Brahim El Bali

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The synthesis, crystal structure, and Raman study of the new dihydrogendiphosphate (NH₄)₂Zn(H₂P ₂O₇) ₂·2H₂O, was reported. Three solutions were mixed in a beaker to prepare the compound, NH ₄OH, ZnCl₂·4H₂O, and K₄P ₂O₇. The Raman spectrum of the mentioned compound was measured in a back-scattering arrangment, under room conditions, using a high throughput holographic imaging filter and a thermoelectrically cooled CCD detector. It was observed that the longest hydrogen bonds occured between the hydroxyl species of the [H₂P₂O₇] groups.

Original language	English
Pages (from-to)	i32-i34
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	3
DOIs	https://doi.org/10.1107/S1600536805004642
State	Published - Mar 2005
Externally published	Yes

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title = "Synthesis, crystal structure and vibrational spectra of a new diammonium zinc(II) dihydrogendiphosphate dihydrate, (NH4)2Zn(H 2P2O7)2·2H2O",

abstract = "The synthesis, crystal structure, and Raman study of the new dihydrogendiphosphate (NH4)2Zn(H2P 2O7) 2·2H2O, was reported. Three solutions were mixed in a beaker to prepare the compound, NH 4OH, ZnCl2·4H2O, and K4P 2O7. The Raman spectrum of the mentioned compound was measured in a back-scattering arrangment, under room conditions, using a high throughput holographic imaging filter and a thermoelectrically cooled CCD detector. It was observed that the longest hydrogen bonds occured between the hydroxyl species of the [H2P2O7] groups.",

author = "Rachid Essehli and Mohammed Lachkar and Ingrid Svoboda and Hartmut Fuess and Bali, \{Brahim El\}",

year = "2005",

month = mar,

doi = "10.1107/S1600536805004642",

language = "English",

volume = "61",

pages = "i32--i34",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "3",

}

Synthesis, crystal structure and vibrational spectra of a new diammonium zinc(II) dihydrogendiphosphate dihydrate, (NH₄)₂Zn(H ₂P₂O₇)₂·2H₂O. / Essehli, Rachid; Lachkar, Mohammed; Svoboda, Ingrid et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 61, No. 3, 03.2005, p. i32-i34.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, crystal structure and vibrational spectra of a new diammonium zinc(II) dihydrogendiphosphate dihydrate, (NH4)2Zn(H 2P2O7)2·2H2O

AU - Essehli, Rachid

AU - Lachkar, Mohammed

AU - Svoboda, Ingrid

AU - Fuess, Hartmut

AU - Bali, Brahim El

PY - 2005/3

Y1 - 2005/3

N2 - The synthesis, crystal structure, and Raman study of the new dihydrogendiphosphate (NH4)2Zn(H2P 2O7) 2·2H2O, was reported. Three solutions were mixed in a beaker to prepare the compound, NH 4OH, ZnCl2·4H2O, and K4P 2O7. The Raman spectrum of the mentioned compound was measured in a back-scattering arrangment, under room conditions, using a high throughput holographic imaging filter and a thermoelectrically cooled CCD detector. It was observed that the longest hydrogen bonds occured between the hydroxyl species of the [H2P2O7] groups.

AB - The synthesis, crystal structure, and Raman study of the new dihydrogendiphosphate (NH4)2Zn(H2P 2O7) 2·2H2O, was reported. Three solutions were mixed in a beaker to prepare the compound, NH 4OH, ZnCl2·4H2O, and K4P 2O7. The Raman spectrum of the mentioned compound was measured in a back-scattering arrangment, under room conditions, using a high throughput holographic imaging filter and a thermoelectrically cooled CCD detector. It was observed that the longest hydrogen bonds occured between the hydroxyl species of the [H2P2O7] groups.

UR - https://www.scopus.com/pages/publications/18544368155

U2 - 10.1107/S1600536805004642

DO - 10.1107/S1600536805004642

M3 - Article

AN - SCOPUS:18544368155

SN - 1600-5368

VL - 61

SP - i32-i34

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

Synthesis, crystal structure and vibrational spectra of a new diammonium zinc(II) dihydrogendiphosphate dihydrate, (NH₄)₂Zn(H ₂P₂O₇)₂·2H₂O

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