Synthesis, Crystal Structure, and Optical Properties of a New Molecular Complex of C60 with a Covalently Linked (FeIIITPP) 2O Dimer

Aleksey L. Litvinov; Dmitri V. Konarev; Andrey Yu Kovalevsky; Alexander N. Lapshin; Evgeniya I. Yudanova; Natalia V. Drichko; Philip Coppens; Rimma N. Lyubovskaya

doi:10.1002/ejic.200300256

Synthesis, Crystal Structure, and Optical Properties of a New Molecular Complex of C₆₀ with a Covalently Linked (Fe^IIITPP) ₂O Dimer

Aleksey L. Litvinov, Dmitri V. Konarev, Andrey Yu Kovalevsky, Alexander N. Lapshin, Evgeniya I. Yudanova, Natalia V. Drichko, Philip Coppens, Rimma N. Lyubovskaya

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19 Scopus citations

Abstract

A new molecular complex of C₆₀ with covalently linked μ- oxo dimer (Fe^IIITPP)₂O are (TPP = tetraphenylporphyrin) was obtained. The complex has a neutral ground state and is formed mainly by van der Waals forces. The X-ray analysis of the crystal structure of the complex showed it to have isolated packing of fullerenes in which each fullerene molecule is embraced in a pocket built by porphyrins. Optical properties and EPR behavior of the complex are described.

Original language	English
Pages (from-to)	3914-3917
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	21
DOIs	https://doi.org/10.1002/ejic.200300256
State	Published - Nov 7 2003
Externally published	Yes

Keywords

Crystal engineering
Fullerenes
Porphyrinoids
Solid-state structures
UV/Vis spectroscopy

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10.1002/ejic.200300256

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Litvinov, A. L., Konarev, D. V., Kovalevsky, A. Y., Lapshin, A. N., Yudanova, E. I., Drichko, N. V., Coppens, P., & Lyubovskaya, R. N. (2003). Synthesis, Crystal Structure, and Optical Properties of a New Molecular Complex of C₆₀ with a Covalently Linked (Fe^IIITPP) ₂O Dimer. European Journal of Inorganic Chemistry, (21), 3914-3917. https://doi.org/10.1002/ejic.200300256

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title = "Synthesis, Crystal Structure, and Optical Properties of a New Molecular Complex of C60 with a Covalently Linked (FeIIITPP) 2O Dimer",

abstract = "A new molecular complex of C60 with covalently linked μ- oxo dimer (FeIIITPP)2O are (TPP = tetraphenylporphyrin) was obtained. The complex has a neutral ground state and is formed mainly by van der Waals forces. The X-ray analysis of the crystal structure of the complex showed it to have isolated packing of fullerenes in which each fullerene molecule is embraced in a pocket built by porphyrins. Optical properties and EPR behavior of the complex are described.",

keywords = "Crystal engineering, Fullerenes, Porphyrinoids, Solid-state structures, UV/Vis spectroscopy",

author = "Litvinov, {Aleksey L.} and Konarev, {Dmitri V.} and Kovalevsky, {Andrey Yu} and Lapshin, {Alexander N.} and Yudanova, {Evgeniya I.} and Drichko, {Natalia V.} and Philip Coppens and Lyubovskaya, {Rimma N.}",

year = "2003",

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day = "7",

doi = "10.1002/ejic.200300256",

language = "English",

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T1 - Synthesis, Crystal Structure, and Optical Properties of a New Molecular Complex of C60 with a Covalently Linked (FeIIITPP) 2O Dimer

AU - Litvinov, Aleksey L.

AU - Konarev, Dmitri V.

AU - Kovalevsky, Andrey Yu

AU - Lapshin, Alexander N.

AU - Yudanova, Evgeniya I.

AU - Drichko, Natalia V.

AU - Coppens, Philip

AU - Lyubovskaya, Rimma N.

PY - 2003/11/7

Y1 - 2003/11/7

N2 - A new molecular complex of C60 with covalently linked μ- oxo dimer (FeIIITPP)2O are (TPP = tetraphenylporphyrin) was obtained. The complex has a neutral ground state and is formed mainly by van der Waals forces. The X-ray analysis of the crystal structure of the complex showed it to have isolated packing of fullerenes in which each fullerene molecule is embraced in a pocket built by porphyrins. Optical properties and EPR behavior of the complex are described.

AB - A new molecular complex of C60 with covalently linked μ- oxo dimer (FeIIITPP)2O are (TPP = tetraphenylporphyrin) was obtained. The complex has a neutral ground state and is formed mainly by van der Waals forces. The X-ray analysis of the crystal structure of the complex showed it to have isolated packing of fullerenes in which each fullerene molecule is embraced in a pocket built by porphyrins. Optical properties and EPR behavior of the complex are described.

KW - Crystal engineering

KW - Fullerenes

KW - Porphyrinoids

KW - Solid-state structures

KW - UV/Vis spectroscopy

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DO - 10.1002/ejic.200300256

M3 - Article

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SN - 1434-1948

SP - 3914

EP - 3917

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 21

ER -

Synthesis, Crystal Structure, and Optical Properties of a New Molecular Complex of C₆₀ with a Covalently Linked (Fe^IIITPP) ₂O Dimer

Abstract

Keywords

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