Synthesis, crystal structure, and magnetic properties of Bi 3Mn4O12(NO3) oxynitrate comprising S = 3/2 honeycomb lattice

Olga Smirnova; Masaki Azuma; Nobuhiro Kumada; Yoshihiro Kusano; Masaaki Matsuda; Yuichi Shimakawa; Takahiro Takei; Yoshinori Yonesaki; Nobukazu Kinomura

doi:10.1021/ja901922p

Synthesis, crystal structure, and magnetic properties of Bi ₃Mn₄O₁₂(NO₃) oxynitrate comprising S = 3/2 honeycomb lattice

Olga Smirnova, Masaki Azuma, Nobuhiro Kumada, Yoshihiro Kusano, Masaaki Matsuda, Yuichi Shimakawa, Takahiro Takei, Yoshinori Yonesaki, Nobukazu Kinomura

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133 Scopus citations

Abstract

Neutron diffraction and FT-IR analysis revealed that the novel oxynitrate Bi₃Mn₄O₁₂(NO₃) (space group P3, a = 4.9692(1) Å, c = 13.1627(3) Å) prepared by hydrothermal synthesis is of a new structural type including flat NO₃ layers alternating with blocks of two PbSb₂O₆-like layers. Mn4+ (S = 3/2) forms a regular honeycomb lattice, and magnetic susceptibility data indicated two-dimensional magnetism. Despite its Weiss constant of -257 K, no long-range ordering was observed down to 0.4 K because of the magnetic frustration due to the competition between the nearest and the next-nearest antiferromagnetic interactions.

Original language	English
Pages (from-to)	8313-8317
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	131
Issue number	23
DOIs	https://doi.org/10.1021/ja901922p
State	Published - Jun 17 2009
Externally published	Yes

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title = "Synthesis, crystal structure, and magnetic properties of Bi 3Mn4O12(NO3) oxynitrate comprising S = 3/2 honeycomb lattice",

abstract = "Neutron diffraction and FT-IR analysis revealed that the novel oxynitrate Bi3Mn4O12(NO3) (space group P3, a = 4.9692(1) {\AA}, c = 13.1627(3) {\AA}) prepared by hydrothermal synthesis is of a new structural type including flat NO3 layers alternating with blocks of two PbSb2O6-like layers. Mn4+ (S = 3/2) forms a regular honeycomb lattice, and magnetic susceptibility data indicated two-dimensional magnetism. Despite its Weiss constant of -257 K, no long-range ordering was observed down to 0.4 K because of the magnetic frustration due to the competition between the nearest and the next-nearest antiferromagnetic interactions.",

author = "Olga Smirnova and Masaki Azuma and Nobuhiro Kumada and Yoshihiro Kusano and Masaaki Matsuda and Yuichi Shimakawa and Takahiro Takei and Yoshinori Yonesaki and Nobukazu Kinomura",

year = "2009",

month = jun,

day = "17",

doi = "10.1021/ja901922p",

language = "English",

volume = "131",

pages = "8313--8317",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Synthesis, crystal structure, and magnetic properties of Bi 3Mn4O12(NO3) oxynitrate comprising S = 3/2 honeycomb lattice

AU - Smirnova, Olga

AU - Azuma, Masaki

AU - Kumada, Nobuhiro

AU - Kusano, Yoshihiro

AU - Matsuda, Masaaki

AU - Shimakawa, Yuichi

AU - Takei, Takahiro

AU - Yonesaki, Yoshinori

AU - Kinomura, Nobukazu

PY - 2009/6/17

Y1 - 2009/6/17

N2 - Neutron diffraction and FT-IR analysis revealed that the novel oxynitrate Bi3Mn4O12(NO3) (space group P3, a = 4.9692(1) Å, c = 13.1627(3) Å) prepared by hydrothermal synthesis is of a new structural type including flat NO3 layers alternating with blocks of two PbSb2O6-like layers. Mn4+ (S = 3/2) forms a regular honeycomb lattice, and magnetic susceptibility data indicated two-dimensional magnetism. Despite its Weiss constant of -257 K, no long-range ordering was observed down to 0.4 K because of the magnetic frustration due to the competition between the nearest and the next-nearest antiferromagnetic interactions.

AB - Neutron diffraction and FT-IR analysis revealed that the novel oxynitrate Bi3Mn4O12(NO3) (space group P3, a = 4.9692(1) Å, c = 13.1627(3) Å) prepared by hydrothermal synthesis is of a new structural type including flat NO3 layers alternating with blocks of two PbSb2O6-like layers. Mn4+ (S = 3/2) forms a regular honeycomb lattice, and magnetic susceptibility data indicated two-dimensional magnetism. Despite its Weiss constant of -257 K, no long-range ordering was observed down to 0.4 K because of the magnetic frustration due to the competition between the nearest and the next-nearest antiferromagnetic interactions.

UR - https://www.scopus.com/pages/publications/67650540763

U2 - 10.1021/ja901922p

DO - 10.1021/ja901922p

M3 - Article

AN - SCOPUS:67650540763

SN - 0002-7863

VL - 131

SP - 8313

EP - 8317

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 23

ER -

Synthesis, crystal structure, and magnetic properties of Bi ₃Mn₄O₁₂(NO₃) oxynitrate comprising S = 3/2 honeycomb lattice

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