Synthesis and structural characterization of a series of uranyl-betaine coordination complexes

Philip A. Smith; Tyler L. Spano; Peter C. Burns

doi:10.1515/zkri-2017-2139

Synthesis and structural characterization of a series of uranyl-betaine coordination complexes

Philip A. Smith, Tyler L. Spano, Peter C. Burns

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Abstract

Trimethylglycine and betainium class ionic liquids were employed in synthesizing six uranyl-betaine coordination complexes: [(μ₂-(CH₃)N₂C₃H₃(CH₂COO))₂ (UO₂(Cl)((CH₃)N₂C₃H₃(CH₂COO)))₂] 2[N(SO₂CF₃)₂] (1), [K][UO₂(Cl)₃((CH₃)₃NCH₂COO)] (2), [(CH₃)₃NCH₂COOH][UO₂(Cl)₃((CH₃)₃NCH₂COO)]?H₂O (3), [LiUO₂(μ₂-(CH₃)₃NCH₂COO)₄] 3[N(SO₂CF₃)₂] (4) {(μ₂-(CH₃)₃NCH₂COO)UO₂(NO₃)₂((CH₃)₃NCH₂COO)}₂ UO₂(NO₃)₂, UO₂(NO₃)₂(H₂O)₂?H₂O (5), and UO₂(Cl)₂(H₂O)(μ₂-(CH₃)₃NCH₂COO) (6). These complexes expound upon the variability of monocarboxyl-functionalized uranyl coordination complexes, providing an enhanced framework for investigations into the structural chemistry of analogous actinyl systems.

Original language	English
Pages (from-to)	507-513
Number of pages	7
Journal	Zeitschrift fur Kristallographie - Crystalline Materials
Volume	233
Issue number	7
DOIs	https://doi.org/10.1515/zkri-2017-2139
State	Published - Jul 26 2018
Externally published	Yes

Funding

Acknowledgements: This research was supported by the Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Science, Office of Science, U.S. Department of Energy, Grant No. DE-FG02-07ER15880. XRF analyses were conducted at the Center for Environmental Science and Technology, and Raman analyses were conducted at the Materials Characterization Facility at the University of Notre Dame.

Funders	Funder number
U.S. Department of Energy	DE-FG02-07ER15880
Office of Science
Basic Energy Sciences
Chemical Sciences, Geosciences, and Biosciences Division

Keywords

betaine
coordination
imidazolium
ionic liquid
uranyl

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title = "Synthesis and structural characterization of a series of uranyl-betaine coordination complexes",

abstract = "Trimethylglycine and betainium class ionic liquids were employed in synthesizing six uranyl-betaine coordination complexes: [(μ2-(CH3)N2C3H3(CH2COO))2 (UO2(Cl)((CH3)N2C3H3(CH2COO)))2] 2[N(SO2CF3)2] (1), [K][UO2(Cl)3((CH3)3NCH2COO)] (2), [(CH3)3NCH2COOH][UO2(Cl)3((CH3)3NCH2COO)]?H2O (3), [LiUO2(μ2-(CH3)3NCH2COO)4] 3[N(SO2CF3)2] (4) {(μ2-(CH3)3NCH2COO)UO2(NO3)2((CH3)3NCH2COO)}2 UO2(NO3)2, UO2(NO3)2(H2O)2?H2O (5), and UO2(Cl)2(H2O)(μ2-(CH3)3NCH2COO) (6). These complexes expound upon the variability of monocarboxyl-functionalized uranyl coordination complexes, providing an enhanced framework for investigations into the structural chemistry of analogous actinyl systems.",

keywords = "betaine, coordination, imidazolium, ionic liquid, uranyl",

author = "Smith, {Philip A.} and Spano, {Tyler L.} and Burns, {Peter C.}",

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doi = "10.1515/zkri-2017-2139",

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T1 - Synthesis and structural characterization of a series of uranyl-betaine coordination complexes

AU - Smith, Philip A.

AU - Spano, Tyler L.

AU - Burns, Peter C.

PY - 2018/7/26

Y1 - 2018/7/26

N2 - Trimethylglycine and betainium class ionic liquids were employed in synthesizing six uranyl-betaine coordination complexes: [(μ2-(CH3)N2C3H3(CH2COO))2 (UO2(Cl)((CH3)N2C3H3(CH2COO)))2] 2[N(SO2CF3)2] (1), [K][UO2(Cl)3((CH3)3NCH2COO)] (2), [(CH3)3NCH2COOH][UO2(Cl)3((CH3)3NCH2COO)]?H2O (3), [LiUO2(μ2-(CH3)3NCH2COO)4] 3[N(SO2CF3)2] (4) {(μ2-(CH3)3NCH2COO)UO2(NO3)2((CH3)3NCH2COO)}2 UO2(NO3)2, UO2(NO3)2(H2O)2?H2O (5), and UO2(Cl)2(H2O)(μ2-(CH3)3NCH2COO) (6). These complexes expound upon the variability of monocarboxyl-functionalized uranyl coordination complexes, providing an enhanced framework for investigations into the structural chemistry of analogous actinyl systems.

AB - Trimethylglycine and betainium class ionic liquids were employed in synthesizing six uranyl-betaine coordination complexes: [(μ2-(CH3)N2C3H3(CH2COO))2 (UO2(Cl)((CH3)N2C3H3(CH2COO)))2] 2[N(SO2CF3)2] (1), [K][UO2(Cl)3((CH3)3NCH2COO)] (2), [(CH3)3NCH2COOH][UO2(Cl)3((CH3)3NCH2COO)]?H2O (3), [LiUO2(μ2-(CH3)3NCH2COO)4] 3[N(SO2CF3)2] (4) {(μ2-(CH3)3NCH2COO)UO2(NO3)2((CH3)3NCH2COO)}2 UO2(NO3)2, UO2(NO3)2(H2O)2?H2O (5), and UO2(Cl)2(H2O)(μ2-(CH3)3NCH2COO) (6). These complexes expound upon the variability of monocarboxyl-functionalized uranyl coordination complexes, providing an enhanced framework for investigations into the structural chemistry of analogous actinyl systems.

KW - betaine

KW - coordination

KW - imidazolium

KW - ionic liquid

KW - uranyl

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M3 - Article

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JO - Zeitschrift fur Kristallographie - Crystalline Materials

JF - Zeitschrift fur Kristallographie - Crystalline Materials

IS - 7

ER -

Synthesis and structural characterization of a series of uranyl-betaine coordination complexes

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