Abstract
High quality superconducting films of YBa2Cu3O7-x were deposited in situ using single target 90° off-axis sputtering. We have investigated their superconducting DC and RF properties, their normal state properties, and their microstructures. These films are distinctly different from bulk crystals and post-deposition annealed films. Sharp superconducting transition temperatures can be reproducibly obtained by control of deposition parameters. The Tc can be varied from 75 to 89 K. The optimization of properties other than Tc and the control of film texture occur under conditions different from those for which the highest Tc is obtained. Normal state conductivities are as high as or higher than those of single crystals. Critical current densities reach 6 × 107 A/cm2 at 4.2 K. All the above properties are relatively insensitive to compositional variations. The Tc's have a much weaker dependence on the c-axis lattice parameters than do those of bulk samples. The measured low-temperature penetration depth is 1400 Å and surface resistance at 4.2 K and 10 GHz is as low as 16 μΩ. Microstructural studies show sharp interfaces between films and their substrates and a variety of defect structures. Many of the properties of in situ films can be explained by clean grain boundaries and the characteristics of the surface growth occuring during in situ deposition.
Original language | English |
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Pages (from-to) | 354-383 |
Number of pages | 30 |
Journal | Physica C: Superconductivity and its Applications |
Volume | 171 |
Issue number | 3-4 |
DOIs | |
State | Published - Nov 1 1990 |
Externally published | Yes |
Funding
support of Profs. Beasley and Kapitulnik and the members of the Stanford Department of Applied Physics KGB group. And, we have also profited from interactions with N. Newman, K. Char and J.M. Rowell. The authors would also like to thank D.L. Keith and W. Holmes for their help in developing the sputtering facility and B.W. Langley for analysis of the penetration depth data. We also thank S. Johnson and coworkers from SRC. Some of the targets used came from material being studied with S. Johnson under support of EPRI and DARPA. The work at Stanford has been supported in part by the Air Force Office for Scientific Research under contract F49620-88-C-004, by the Stanford Center for Materials Research under the NSF-MRL program, and by the Electric Power Research Institute Grant RP8009-11.