Synthesis and extraction behaviour of calix[4]arenes partially substituted at the wide rim by carbamoylmethylphosphine oxide (CMPO) functions

Françoise Arnaud-Neu; Silvia Barboso; Volker Böhmer; Frédéric Brisach; Laetitia Delmau; Jean François Dozol; Oliver Mogck; Erich F. Paulus; Mohamed Saadioui; Alexander Shivanyuk

doi:10.1071/CH03163

Synthesis and extraction behaviour of calix[4]arenes partially substituted at the wide rim by carbamoylmethylphosphine oxide (CMPO) functions

Françoise Arnaud-Neu
, Silvia Barboso
, Volker Böhmer
, Frédéric Brisach
, Laetitia Delmau
, Jean François Dozol
, Oliver Mogck
, Erich F. Paulus
, Mohamed Saadioui
, Alexander Shivanyuk

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Tetraethers of calix[4]arenes fixed in the cone conformation and substituted at their wide rim by one to three CMPO residues and hydrogen atoms or t-butyl moieties in the remaining position(s) were synthesized. Liquid/liquid extraction studies of selected lanthanides and actinides were undertaken with these calix[4]arenes, including also a linear trimer, in order to obtain a better understanding for the extraction properties of the corresponding calix[4]arene substituted by four CMPO functions. The structure of the 1,3-di-CMPO derivative was confirmed by single crystal X-ray analysis.

Original language	English
Pages (from-to)	1113-1119
Number of pages	7
Journal	Australian Journal of Chemistry
Volume	56
Issue number	11
DOIs	https://doi.org/10.1071/CH03163
State	Published - 2003
Externally published	Yes

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10.1071/CH03163

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Arnaud-Neu, F., Barboso, S., Böhmer, V., Brisach, F., Delmau, L., Dozol, J. F., Mogck, O., Paulus, E. F., Saadioui, M., & Shivanyuk, A. (2003). Synthesis and extraction behaviour of calix[4]arenes partially substituted at the wide rim by carbamoylmethylphosphine oxide (CMPO) functions. Australian Journal of Chemistry, 56(11), 1113-1119. https://doi.org/10.1071/CH03163

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abstract = "Tetraethers of calix[4]arenes fixed in the cone conformation and substituted at their wide rim by one to three CMPO residues and hydrogen atoms or t-butyl moieties in the remaining position(s) were synthesized. Liquid/liquid extraction studies of selected lanthanides and actinides were undertaken with these calix[4]arenes, including also a linear trimer, in order to obtain a better understanding for the extraction properties of the corresponding calix[4]arene substituted by four CMPO functions. The structure of the 1,3-di-CMPO derivative was confirmed by single crystal X-ray analysis.",

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year = "2003",

doi = "10.1071/CH03163",

language = "English",

volume = "56",

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journal = "Australian Journal of Chemistry",

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T1 - Synthesis and extraction behaviour of calix[4]arenes partially substituted at the wide rim by carbamoylmethylphosphine oxide (CMPO) functions

AU - Arnaud-Neu, Françoise

AU - Barboso, Silvia

AU - Böhmer, Volker

AU - Brisach, Frédéric

AU - Delmau, Laetitia

AU - Dozol, Jean François

AU - Mogck, Oliver

AU - Paulus, Erich F.

AU - Saadioui, Mohamed

AU - Shivanyuk, Alexander

PY - 2003

Y1 - 2003

N2 - Tetraethers of calix[4]arenes fixed in the cone conformation and substituted at their wide rim by one to three CMPO residues and hydrogen atoms or t-butyl moieties in the remaining position(s) were synthesized. Liquid/liquid extraction studies of selected lanthanides and actinides were undertaken with these calix[4]arenes, including also a linear trimer, in order to obtain a better understanding for the extraction properties of the corresponding calix[4]arene substituted by four CMPO functions. The structure of the 1,3-di-CMPO derivative was confirmed by single crystal X-ray analysis.

AB - Tetraethers of calix[4]arenes fixed in the cone conformation and substituted at their wide rim by one to three CMPO residues and hydrogen atoms or t-butyl moieties in the remaining position(s) were synthesized. Liquid/liquid extraction studies of selected lanthanides and actinides were undertaken with these calix[4]arenes, including also a linear trimer, in order to obtain a better understanding for the extraction properties of the corresponding calix[4]arene substituted by four CMPO functions. The structure of the 1,3-di-CMPO derivative was confirmed by single crystal X-ray analysis.

UR - https://www.scopus.com/pages/publications/0344153454

U2 - 10.1071/CH03163

DO - 10.1071/CH03163

M3 - Article

AN - SCOPUS:0344153454

SN - 0004-9425

VL - 56

SP - 1113

EP - 1119

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 11

ER -

Synthesis and extraction behaviour of calix[4]arenes partially substituted at the wide rim by carbamoylmethylphosphine oxide (CMPO) functions

Abstract

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