Synthesis and characterization of thiazolium-based room temperature ionic liquids for gas separations

Patrick C. Hillesheim; Shannon M. Mahurin; Pasquale F. Fulvio; Joshua S. Yeary; Yatsandra Oyola; De En Jiang; Sheng Dai

doi:10.1021/ie3015632

Synthesis and characterization of thiazolium-based room temperature ionic liquids for gas separations

Patrick C. Hillesheim
, Shannon M. Mahurin
, Pasquale F. Fulvio
, Joshua S. Yeary
, Yatsandra Oyola
, De En Jiang
, Sheng Dai

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

A series of novel thiazolium-bis(triflamide) based ionic liquids has been synthesized and characterized. Physicochemical properties of the ionic liquids such as thermal stability, phase transitions, and infrared spectra were analyzed and compared to the imidazolium-based congeners. Several unique classes of ancillary substitutions are examined with respect to impacts on overall structure, in addition to their carbon dioxide absorption properties in supported ionic-liquid membranes for gas separation.

Original language	English
Pages (from-to)	11530-11537
Number of pages	8
Journal	Industrial and Engineering Chemistry Research
Volume	51
Issue number	35
DOIs	https://doi.org/10.1021/ie3015632
State	Published - Sep 5 2012

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title = "Synthesis and characterization of thiazolium-based room temperature ionic liquids for gas separations",

abstract = "A series of novel thiazolium-bis(triflamide) based ionic liquids has been synthesized and characterized. Physicochemical properties of the ionic liquids such as thermal stability, phase transitions, and infrared spectra were analyzed and compared to the imidazolium-based congeners. Several unique classes of ancillary substitutions are examined with respect to impacts on overall structure, in addition to their carbon dioxide absorption properties in supported ionic-liquid membranes for gas separation.",

author = "Hillesheim, \{Patrick C.\} and Mahurin, \{Shannon M.\} and Fulvio, \{Pasquale F.\} and Yeary, \{Joshua S.\} and Yatsandra Oyola and Jiang, \{De En\} and Sheng Dai",

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T1 - Synthesis and characterization of thiazolium-based room temperature ionic liquids for gas separations

AU - Hillesheim, Patrick C.

AU - Mahurin, Shannon M.

AU - Fulvio, Pasquale F.

AU - Yeary, Joshua S.

AU - Oyola, Yatsandra

AU - Jiang, De En

AU - Dai, Sheng

PY - 2012/9/5

Y1 - 2012/9/5

N2 - A series of novel thiazolium-bis(triflamide) based ionic liquids has been synthesized and characterized. Physicochemical properties of the ionic liquids such as thermal stability, phase transitions, and infrared spectra were analyzed and compared to the imidazolium-based congeners. Several unique classes of ancillary substitutions are examined with respect to impacts on overall structure, in addition to their carbon dioxide absorption properties in supported ionic-liquid membranes for gas separation.

AB - A series of novel thiazolium-bis(triflamide) based ionic liquids has been synthesized and characterized. Physicochemical properties of the ionic liquids such as thermal stability, phase transitions, and infrared spectra were analyzed and compared to the imidazolium-based congeners. Several unique classes of ancillary substitutions are examined with respect to impacts on overall structure, in addition to their carbon dioxide absorption properties in supported ionic-liquid membranes for gas separation.

UR - https://www.scopus.com/pages/publications/84865847880

U2 - 10.1021/ie3015632

DO - 10.1021/ie3015632

M3 - Article

AN - SCOPUS:84865847880

SN - 0888-5885

VL - 51

SP - 11530

EP - 11537

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 35

ER -

Synthesis and characterization of thiazolium-based room temperature ionic liquids for gas separations

Abstract

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