Synthesis and characterization of cerium(IV) metallocenes

Andrew D. Sutton; David L. Clark; Brian L. Scott; John C. Gordon

doi:10.3390/inorganics3040589

Synthesis and characterization of cerium(IV) metallocenes

Andrew D. Sutton
, David L. Clark
, Brian L. Scott
, John C. Gordon

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

By applying a salt metathesis approach between Ce(O^tBu₃)₂(NO₃)₂(THF)₂ and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.

Original language	English
Pages (from-to)	589-596
Number of pages	8
Journal	Inorganics
Volume	3
Issue number	4
DOIs	https://doi.org/10.3390/inorganics3040589
State	Published - Dec 1 2015
Externally published	Yes

Keywords

Cerium
Crystal structure
Cyclopentadiene
Organometallic

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10.3390/inorganics3040589

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title = "Synthesis and characterization of cerium(IV) metallocenes",

abstract = "By applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.",

keywords = "Cerium, Crystal structure, Cyclopentadiene, Organometallic",

author = "Sutton, \{Andrew D.\} and Clark, \{David L.\} and Scott, \{Brian L.\} and Gordon, \{John C.\}",

note = "Publisher Copyright: {\textcopyright} 2015 by the authors; licensee MDPI, Basel, Switzerland.",

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doi = "10.3390/inorganics3040589",

language = "English",

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T1 - Synthesis and characterization of cerium(IV) metallocenes

AU - Sutton, Andrew D.

AU - Clark, David L.

AU - Scott, Brian L.

AU - Gordon, John C.

PY - 2015/12/1

Y1 - 2015/12/1

N2 - By applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.

AB - By applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.

KW - Cerium

KW - Crystal structure

KW - Cyclopentadiene

KW - Organometallic

UR - https://www.scopus.com/pages/publications/85014383777

U2 - 10.3390/inorganics3040589

DO - 10.3390/inorganics3040589

M3 - Article

AN - SCOPUS:85014383777

SN - 2304-6740

VL - 3

SP - 589

EP - 596

JO - Inorganics

JF - Inorganics

IS - 4

ER -

Synthesis and characterization of cerium(IV) metallocenes

Abstract

Keywords

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