Syntheses, structures, and 1H, 13C{1H} and 119Sn{1H} NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds

Alejandro G. Lichtscheidl; Michael T. Janicke; Brian L. Scott; Andrew T. Nelson; Jaqueline L. Kiplinger

doi:10.1039/c5dt01980j

Syntheses, structures, and ¹H, ¹³C{¹H} and ¹¹⁹Sn{¹H} NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds

Alejandro G. Lichtscheidl
, Michael T. Janicke
, Brian L. Scott
, Andrew T. Nelson
, Jaqueline L. Kiplinger

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The synthesis and full characterization, including Nuclear Magnetic Resonance (NMR) data (¹H, ¹³C{¹H} and ¹¹⁹Sn{¹H}), for a series of Me₃SnX (X = O-2,6-^tBu₂C₆H₃ (1), (Me₃Sn)N(2,6-ⁱPr₂C₆H₃) (3), NH-2,4,6-^tBu₃C₆H₂ (4), N(SiMe₃)₂ (5), NEt₂, C₅Me₅ (6), Cl, Br, I, and SnMe₃) compounds in benzene-d₆, toluene-d₈, dichloromethane-d₂, chloroform-d₁, acetonitrile-d₃, and tetrahydrofuran-d₈ are reported. The X-ray crystal structures of Me₃Sn(O-2,6-^tBu₂C₆H₃) (1), Me₃Sn(O-2,6-ⁱPr₂C₆H₃) (2), and (Me₃Sn)(NH-2,4,6-^tBu₃C₆H₂) (4) are also presented. These compiled data complement existing literature data and ease the characterization of these compounds by routine NMR experiments.

Original language	English
Pages (from-to)	16156-16163
Number of pages	8
Journal	Dalton Transactions
Volume	44
Issue number	36
DOIs	https://doi.org/10.1039/c5dt01980j
State	Published - Aug 6 2015
Externally published	Yes

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@article{8cc1e80dc29542619d88b7f182153cad,

title = "Syntheses, structures, and 1H, 13C\{1H\} and 119Sn\{1H\} NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds",

abstract = "The synthesis and full characterization, including Nuclear Magnetic Resonance (NMR) data (1H, 13C\{1H\} and 119Sn\{1H\}), for a series of Me3SnX (X = O-2,6-tBu2C6H3 (1), (Me3Sn)N(2,6-iPr2C6H3) (3), NH-2,4,6-tBu3C6H2 (4), N(SiMe3)2 (5), NEt2, C5Me5 (6), Cl, Br, I, and SnMe3) compounds in benzene-d6, toluene-d8, dichloromethane-d2, chloroform-d1, acetonitrile-d3, and tetrahydrofuran-d8 are reported. The X-ray crystal structures of Me3Sn(O-2,6-tBu2C6H3) (1), Me3Sn(O-2,6-iPr2C6H3) (2), and (Me3Sn)(NH-2,4,6-tBu3C6H2) (4) are also presented. These compiled data complement existing literature data and ease the characterization of these compounds by routine NMR experiments.",

author = "Lichtscheidl, \{Alejandro G.\} and Janicke, \{Michael T.\} and Scott, \{Brian L.\} and Nelson, \{Andrew T.\} and Kiplinger, \{Jaqueline L.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

month = aug,

day = "6",

doi = "10.1039/c5dt01980j",

language = "English",

volume = "44",

pages = "16156--16163",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "36",

}

TY - JOUR

T1 - Syntheses, structures, and 1H, 13C{1H} and 119Sn{1H} NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds

AU - Lichtscheidl, Alejandro G.

AU - Janicke, Michael T.

AU - Scott, Brian L.

AU - Nelson, Andrew T.

AU - Kiplinger, Jaqueline L.

PY - 2015/8/6

Y1 - 2015/8/6

N2 - The synthesis and full characterization, including Nuclear Magnetic Resonance (NMR) data (1H, 13C{1H} and 119Sn{1H}), for a series of Me3SnX (X = O-2,6-tBu2C6H3 (1), (Me3Sn)N(2,6-iPr2C6H3) (3), NH-2,4,6-tBu3C6H2 (4), N(SiMe3)2 (5), NEt2, C5Me5 (6), Cl, Br, I, and SnMe3) compounds in benzene-d6, toluene-d8, dichloromethane-d2, chloroform-d1, acetonitrile-d3, and tetrahydrofuran-d8 are reported. The X-ray crystal structures of Me3Sn(O-2,6-tBu2C6H3) (1), Me3Sn(O-2,6-iPr2C6H3) (2), and (Me3Sn)(NH-2,4,6-tBu3C6H2) (4) are also presented. These compiled data complement existing literature data and ease the characterization of these compounds by routine NMR experiments.

AB - The synthesis and full characterization, including Nuclear Magnetic Resonance (NMR) data (1H, 13C{1H} and 119Sn{1H}), for a series of Me3SnX (X = O-2,6-tBu2C6H3 (1), (Me3Sn)N(2,6-iPr2C6H3) (3), NH-2,4,6-tBu3C6H2 (4), N(SiMe3)2 (5), NEt2, C5Me5 (6), Cl, Br, I, and SnMe3) compounds in benzene-d6, toluene-d8, dichloromethane-d2, chloroform-d1, acetonitrile-d3, and tetrahydrofuran-d8 are reported. The X-ray crystal structures of Me3Sn(O-2,6-tBu2C6H3) (1), Me3Sn(O-2,6-iPr2C6H3) (2), and (Me3Sn)(NH-2,4,6-tBu3C6H2) (4) are also presented. These compiled data complement existing literature data and ease the characterization of these compounds by routine NMR experiments.

UR - https://www.scopus.com/pages/publications/84940739559

U2 - 10.1039/c5dt01980j

DO - 10.1039/c5dt01980j

M3 - Article

AN - SCOPUS:84940739559

SN - 1477-9226

VL - 44

SP - 16156

EP - 16163

JO - Dalton Transactions

JF - Dalton Transactions

IS - 36

ER -

Syntheses, structures, and ¹H, ¹³C{¹H} and ¹¹⁹Sn{¹H} NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds

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