Syntheses, spectroscopic data, and X-ray diffraction structures of the heterometallic RuRe face-shared bioctahedral (η6-cymene)Ru(μ- Cl)3Re(CO)3 and MnRu2 Edge-shared trioctahedral [fac-ClRu(CO)3]2(μ-Cl)4Mn(H 2O)2 complexes

Xiaoping Wang; Sean W. Hunt; Michael G. Richmond

doi:10.1007/s10870-009-9535-y

Syntheses, spectroscopic data, and X-ray diffraction structures of the heterometallic RuRe face-shared bioctahedral (η⁶-cymene)Ru(μ- Cl)₃Re(CO)₃ and MnRu₂ Edge-shared trioctahedral [fac-ClRu(CO)₃]₂(μ-Cl)₄Mn(H ₂O)₂ complexes

Xiaoping Wang, Sean W. Hunt, Michael G. Richmond

Single Crystal Diffraction

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Thermolysis of the diruthenium compound [(η⁶-cymene) RuCl₂]₂ (1) with ClRe(CO)₅ (2) leads to the formation of the new confacial bioctahedral compound (η⁶-cymene) Ru(μ-Cl)₃Re(CO)₃ (3) in good yields; the same product has also been isolated when a mixture of 1 and 2 is irradiated with near UV-vis light for an extended period of time. Heating 1 and ClMn(CO)₅ (4) does not furnish the corresponding manganese analogue of 3 but rather the trioctahedral halide-bridged product [fac-ClRu(CO)₃] ₂(μ-Cl)₄Mn(H₂O)₂ (5). 3 and 5 have been fully characterized in solution and their molecular structures established by X-ray crystallography. Graphical Abstract: Thermolysis of [(η⁶-cymene)RuCl₂]₂ (1) with the respective pentacarbonyl ClM(CO)₅ [where M = Re (2); Mn(4)] affords the halide-bridged compounds (η⁶-cymene)Ru(μ-Cl) ₃Re(CO)₃ (3) and [fac-ClRu(CO)₃] ₂(μ-Cl)₄Mn(H₂O)₂ (5). 3 and 5 have been isolated and characterized spectroscopically in solution and their molecular structures established by X-ray crystallography. [Figure not available: see fulltext.]

Original language	English
Pages (from-to)	589-594
Number of pages	6
Journal	Journal of Chemical Crystallography
Volume	39
Issue number	8
DOIs	https://doi.org/10.1007/s10870-009-9535-y
State	Published - Aug 2009

Funding

Acknowledgments Financial support from the Robert A. Welch Foundation (Grant B-1093-MGR) is much appreciated.

Funders	Funder number
Robert A. Welch Foundation	B-1093-MGR

Keywords

Halide-bridged compounds
Manganese-ruthenium compounds
Mixed-metal compounds
Ruthenium-rhenium compounds
X-ray crystallography

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Wang, X., Hunt, S. W., & Richmond, M. G. (2009). Syntheses, spectroscopic data, and X-ray diffraction structures of the heterometallic RuRe face-shared bioctahedral (η⁶-cymene)Ru(μ- Cl)₃Re(CO)₃ and MnRu₂ Edge-shared trioctahedral [fac-ClRu(CO)₃]₂(μ-Cl)₄Mn(H ₂O)₂ complexes. Journal of Chemical Crystallography, 39(8), 589-594. https://doi.org/10.1007/s10870-009-9535-y

@article{5b7a5d666216440c90b0444ccff65194,

title = "Syntheses, spectroscopic data, and X-ray diffraction structures of the heterometallic RuRe face-shared bioctahedral (η6-cymene)Ru(μ- Cl)3Re(CO)3 and MnRu2 Edge-shared trioctahedral [fac-ClRu(CO)3]2(μ-Cl)4Mn(H 2O)2 complexes",

abstract = "Thermolysis of the diruthenium compound [(η6-cymene) RuCl2]2 (1) with ClRe(CO)5 (2) leads to the formation of the new confacial bioctahedral compound (η6-cymene) Ru(μ-Cl)3Re(CO)3 (3) in good yields; the same product has also been isolated when a mixture of 1 and 2 is irradiated with near UV-vis light for an extended period of time. Heating 1 and ClMn(CO)5 (4) does not furnish the corresponding manganese analogue of 3 but rather the trioctahedral halide-bridged product [fac-ClRu(CO)3] 2(μ-Cl)4Mn(H2O)2 (5). 3 and 5 have been fully characterized in solution and their molecular structures established by X-ray crystallography. Graphical Abstract: Thermolysis of [(η6-cymene)RuCl2]2 (1) with the respective pentacarbonyl ClM(CO)5 [where M = Re (2); Mn(4)] affords the halide-bridged compounds (η6-cymene)Ru(μ-Cl) 3Re(CO)3 (3) and [fac-ClRu(CO)3] 2(μ-Cl)4Mn(H2O)2 (5). 3 and 5 have been isolated and characterized spectroscopically in solution and their molecular structures established by X-ray crystallography. [Figure not available: see fulltext.]",

keywords = "Halide-bridged compounds, Manganese-ruthenium compounds, Mixed-metal compounds, Ruthenium-rhenium compounds, X-ray crystallography",

author = "Xiaoping Wang and Hunt, {Sean W.} and Richmond, {Michael G.}",

year = "2009",

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Wang, X, Hunt, SW & Richmond, MG 2009, 'Syntheses, spectroscopic data, and X-ray diffraction structures of the heterometallic RuRe face-shared bioctahedral (η⁶-cymene)Ru(μ- Cl)₃Re(CO)₃ and MnRu₂ Edge-shared trioctahedral [fac-ClRu(CO)₃]₂(μ-Cl)₄Mn(H ₂O)₂ complexes', Journal of Chemical Crystallography, vol. 39, no. 8, pp. 589-594. https://doi.org/10.1007/s10870-009-9535-y

Syntheses, spectroscopic data, and X-ray diffraction structures of the heterometallic RuRe face-shared bioctahedral (η⁶-cymene)Ru(μ- Cl)₃Re(CO)₃ and MnRu₂ Edge-shared trioctahedral [fac-ClRu(CO)₃]₂(μ-Cl)₄Mn(H ₂O)₂ complexes. / Wang, Xiaoping; Hunt, Sean W.; Richmond, Michael G.
In: Journal of Chemical Crystallography, Vol. 39, No. 8, 08.2009, p. 589-594.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Syntheses, spectroscopic data, and X-ray diffraction structures of the heterometallic RuRe face-shared bioctahedral (η6-cymene)Ru(μ- Cl)3Re(CO)3 and MnRu2 Edge-shared trioctahedral [fac-ClRu(CO)3]2(μ-Cl)4Mn(H 2O)2 complexes

AU - Wang, Xiaoping

AU - Hunt, Sean W.

AU - Richmond, Michael G.

PY - 2009/8

Y1 - 2009/8

N2 - Thermolysis of the diruthenium compound [(η6-cymene) RuCl2]2 (1) with ClRe(CO)5 (2) leads to the formation of the new confacial bioctahedral compound (η6-cymene) Ru(μ-Cl)3Re(CO)3 (3) in good yields; the same product has also been isolated when a mixture of 1 and 2 is irradiated with near UV-vis light for an extended period of time. Heating 1 and ClMn(CO)5 (4) does not furnish the corresponding manganese analogue of 3 but rather the trioctahedral halide-bridged product [fac-ClRu(CO)3] 2(μ-Cl)4Mn(H2O)2 (5). 3 and 5 have been fully characterized in solution and their molecular structures established by X-ray crystallography. Graphical Abstract: Thermolysis of [(η6-cymene)RuCl2]2 (1) with the respective pentacarbonyl ClM(CO)5 [where M = Re (2); Mn(4)] affords the halide-bridged compounds (η6-cymene)Ru(μ-Cl) 3Re(CO)3 (3) and [fac-ClRu(CO)3] 2(μ-Cl)4Mn(H2O)2 (5). 3 and 5 have been isolated and characterized spectroscopically in solution and their molecular structures established by X-ray crystallography. [Figure not available: see fulltext.]

AB - Thermolysis of the diruthenium compound [(η6-cymene) RuCl2]2 (1) with ClRe(CO)5 (2) leads to the formation of the new confacial bioctahedral compound (η6-cymene) Ru(μ-Cl)3Re(CO)3 (3) in good yields; the same product has also been isolated when a mixture of 1 and 2 is irradiated with near UV-vis light for an extended period of time. Heating 1 and ClMn(CO)5 (4) does not furnish the corresponding manganese analogue of 3 but rather the trioctahedral halide-bridged product [fac-ClRu(CO)3] 2(μ-Cl)4Mn(H2O)2 (5). 3 and 5 have been fully characterized in solution and their molecular structures established by X-ray crystallography. Graphical Abstract: Thermolysis of [(η6-cymene)RuCl2]2 (1) with the respective pentacarbonyl ClM(CO)5 [where M = Re (2); Mn(4)] affords the halide-bridged compounds (η6-cymene)Ru(μ-Cl) 3Re(CO)3 (3) and [fac-ClRu(CO)3] 2(μ-Cl)4Mn(H2O)2 (5). 3 and 5 have been isolated and characterized spectroscopically in solution and their molecular structures established by X-ray crystallography. [Figure not available: see fulltext.]

KW - Halide-bridged compounds

KW - Manganese-ruthenium compounds

KW - Mixed-metal compounds

KW - Ruthenium-rhenium compounds

KW - X-ray crystallography

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