TY - JOUR
T1 - Synergistic effects of water and SO2 on degradation of MIL-125 in the presence of acid gases
AU - Mounfield, William P.
AU - Han, Chu
AU - Pang, Simon H.
AU - Tumuluri, Uma
AU - Jiao, Yang
AU - Bhattacharyya, Souryadeep
AU - Dutzer, Michael R.
AU - Nair, Sankar
AU - Wu, Zili
AU - Lively, Ryan P.
AU - Sholl, David S.
AU - Walton, Krista S.
N1 - Publisher Copyright:
© 2016 American Chemical Society.
PY - 2016/12/8
Y1 - 2016/12/8
N2 - The behavior of metal-organic frameworks (MOFs) in the presence of acid gases may be decisive in their suitability for industrial applications. In this study, MIL-125 and MIL-125-NH2 were investigated with SO2 exposure in dry, humid, and aqueous environments. MIL-125 was found to be unstable in both humid and aqueous acidic environments, while MIL-125-NH2 was stable under these exposure conditions, showing no change in textural properties or visual degradation, as observed through SEM. Both materials were stable in the presence of water and dry SO2, suggesting that the reaction of these molecules to form an acidic species is likely a key factor in the degradation of MIL-125. In situ IR experiments confirmed the presence of sulfite species, supporting the hypothesis that the presence of an acidic sulfur species likely leads to the degradation of the MIL-125 structure. Computational investigation of several potential reaction mechanisms in MIL-125 indicated reactions involving the bisulfite ion are favored over reactions with water or SO2. DFT simulations support the observation that MIL-125-NH2 is stable in humid conditions, as all reactions are less favorable with the functionalized framework compared to the unfunctionalized framework. This combined experimental and computational study advances the fundamental understanding of MOF degradation mechanisms during acid gas exposure.
AB - The behavior of metal-organic frameworks (MOFs) in the presence of acid gases may be decisive in their suitability for industrial applications. In this study, MIL-125 and MIL-125-NH2 were investigated with SO2 exposure in dry, humid, and aqueous environments. MIL-125 was found to be unstable in both humid and aqueous acidic environments, while MIL-125-NH2 was stable under these exposure conditions, showing no change in textural properties or visual degradation, as observed through SEM. Both materials were stable in the presence of water and dry SO2, suggesting that the reaction of these molecules to form an acidic species is likely a key factor in the degradation of MIL-125. In situ IR experiments confirmed the presence of sulfite species, supporting the hypothesis that the presence of an acidic sulfur species likely leads to the degradation of the MIL-125 structure. Computational investigation of several potential reaction mechanisms in MIL-125 indicated reactions involving the bisulfite ion are favored over reactions with water or SO2. DFT simulations support the observation that MIL-125-NH2 is stable in humid conditions, as all reactions are less favorable with the functionalized framework compared to the unfunctionalized framework. This combined experimental and computational study advances the fundamental understanding of MOF degradation mechanisms during acid gas exposure.
UR - https://www.scopus.com/pages/publications/85015246235
U2 - 10.1021/acs.jpcc.6b09264
DO - 10.1021/acs.jpcc.6b09264
M3 - Article
AN - SCOPUS:85015246235
SN - 1932-7447
VL - 120
SP - 27230
EP - 27240
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
IS - 48
ER -