Sustainable synthesis of alkaline metal oxide-mesoporous carbons via mechanochemical coordination self-assembly

Weida Shan; Pengfei Zhang; Shize Yang; Huiyuan Zhu; Peiwen Wu; Huabin Xing; Sheng Dai

doi:10.1039/c7ta08994e

Sustainable synthesis of alkaline metal oxide-mesoporous carbons via mechanochemical coordination self-assembly

Weida Shan, Pengfei Zhang, Shize Yang, Huiyuan Zhu, Peiwen Wu, Huabin Xing, Sheng Dai

Chemical Sciences Division

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A simple, solvent-free, solid-state self-assembly strategy for the synthesis of alkaline-metal-oxide-doped mesoporous carbons (MCs) with tunable mesopores (∼5-9 nm), high surface areas (up to 571 m² g^-1) and large pore volumes (up to 0.65 cm³ g^-1) is developed via mechanochemical assembly between polyphenol-Ca²⁺/Mg²⁺ composites and F127 copolymers. Interestingly, the as-made MgO-MCs not only offer good CO₂ capacities (up to 1.6 mmol g^-1 at 0.15 bar and 273 K) and competitive CO₂/N₂ selectivities (up to 41) but also exhibit high dye adsorption capacities (541 mg g^-1 for methylene blue and 435 mg g^-1 for methyl orange).

Original language	English
Pages (from-to)	23446-23452
Number of pages	7
Journal	Journal of Materials Chemistry A
Volume	5
Issue number	45
DOIs	https://doi.org/10.1039/c7ta08994e
State	Published - 2017

Funding

P. F. Z. and S. D. were supported nancially by the Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, US Department of Energy (DOE). W. S. was supported by China Scholarship Council. P. F. Z. acknowledges Shanghai Pujiang Program (Grant No. 17PJ1403500) and National Natural Science Foundation of China (Grant No. 21776174) for the partial support.

Funders	Funder number
Office of Basic Energy Sciences
Shanghai Pujiang Program	17PJ1403500
US Department of Energy
U.S. Department of Energy
Chemical Sciences, Geosciences, and Biosciences Division
National Natural Science Foundation of China	21776174
China Scholarship Council

Access to Document

10.1039/c7ta08994e

Cite this

@article{78375d410a5f4317b0acf81d055a2b60,

title = "Sustainable synthesis of alkaline metal oxide-mesoporous carbons via mechanochemical coordination self-assembly",

abstract = "A simple, solvent-free, solid-state self-assembly strategy for the synthesis of alkaline-metal-oxide-doped mesoporous carbons (MCs) with tunable mesopores (∼5-9 nm), high surface areas (up to 571 m2 g-1) and large pore volumes (up to 0.65 cm3 g-1) is developed via mechanochemical assembly between polyphenol-Ca2+/Mg2+ composites and F127 copolymers. Interestingly, the as-made MgO-MCs not only offer good CO2 capacities (up to 1.6 mmol g-1 at 0.15 bar and 273 K) and competitive CO2/N2 selectivities (up to 41) but also exhibit high dye adsorption capacities (541 mg g-1 for methylene blue and 435 mg g-1 for methyl orange).",

author = "Weida Shan and Pengfei Zhang and Shize Yang and Huiyuan Zhu and Peiwen Wu and Huabin Xing and Sheng Dai",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7ta08994e",

language = "English",

volume = "5",

pages = "23446--23452",

journal = "Journal of Materials Chemistry A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

number = "45",

}

TY - JOUR

T1 - Sustainable synthesis of alkaline metal oxide-mesoporous carbons via mechanochemical coordination self-assembly

AU - Shan, Weida

AU - Zhang, Pengfei

AU - Yang, Shize

AU - Zhu, Huiyuan

AU - Wu, Peiwen

AU - Xing, Huabin

AU - Dai, Sheng

PY - 2017

Y1 - 2017

N2 - A simple, solvent-free, solid-state self-assembly strategy for the synthesis of alkaline-metal-oxide-doped mesoporous carbons (MCs) with tunable mesopores (∼5-9 nm), high surface areas (up to 571 m2 g-1) and large pore volumes (up to 0.65 cm3 g-1) is developed via mechanochemical assembly between polyphenol-Ca2+/Mg2+ composites and F127 copolymers. Interestingly, the as-made MgO-MCs not only offer good CO2 capacities (up to 1.6 mmol g-1 at 0.15 bar and 273 K) and competitive CO2/N2 selectivities (up to 41) but also exhibit high dye adsorption capacities (541 mg g-1 for methylene blue and 435 mg g-1 for methyl orange).

AB - A simple, solvent-free, solid-state self-assembly strategy for the synthesis of alkaline-metal-oxide-doped mesoporous carbons (MCs) with tunable mesopores (∼5-9 nm), high surface areas (up to 571 m2 g-1) and large pore volumes (up to 0.65 cm3 g-1) is developed via mechanochemical assembly between polyphenol-Ca2+/Mg2+ composites and F127 copolymers. Interestingly, the as-made MgO-MCs not only offer good CO2 capacities (up to 1.6 mmol g-1 at 0.15 bar and 273 K) and competitive CO2/N2 selectivities (up to 41) but also exhibit high dye adsorption capacities (541 mg g-1 for methylene blue and 435 mg g-1 for methyl orange).

UR - http://www.scopus.com/inward/record.url?scp=85035014713&partnerID=8YFLogxK

U2 - 10.1039/c7ta08994e

DO - 10.1039/c7ta08994e

M3 - Article

AN - SCOPUS:85035014713

SN - 2050-7488

VL - 5

SP - 23446

EP - 23452

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 45

ER -

Sustainable synthesis of alkaline metal oxide-mesoporous carbons via mechanochemical coordination self-assembly

Abstract

Funding

Access to Document

Other files and links

Fingerprint

Cite this