Supramolecular traps for highly phosphorylated inositol sources of phosphorus

Subhamay Pramanik; Victor W. Day; Kristin Bowman-James

doi:10.1039/c9cc09321d

Supramolecular traps for highly phosphorylated inositol sources of phosphorus

Subhamay Pramanik, Victor W. Day, Kristin Bowman-James

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Structurally elusive inositol hexakisphosphates have been trapped in host-guest sandwiches between two picolinamide macrocycles that remain intact in solution, aided by hydrogen bonds and electrostatic interactions. This first report of macrocyclic complexes of inositol hexakisphosphates provides structural insight to significant biosources of phosphorus that impact the global phosphorus cycle.

Original language	English
Pages (from-to)	3269-3272
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	22
DOIs	https://doi.org/10.1039/c9cc09321d
State	Published - Mar 18 2020
Externally published	Yes

Funding

The authors thank the National Science Foundation (CHE-1710535) for support of this work and (CHE-0923449) for the purchase of the X-ray diffractometer. The authors thank Dr Justin T. Douglas, Director of the NMR Laboratory at the University of Kansas, for helpful NMR discussions.

Funders	Funder number
National Science Foundation	CHE-0923449, 1710535, CHE-1710535
National Science Foundation

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10.1039/c9cc09321d

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title = "Supramolecular traps for highly phosphorylated inositol sources of phosphorus",

abstract = "Structurally elusive inositol hexakisphosphates have been trapped in host-guest sandwiches between two picolinamide macrocycles that remain intact in solution, aided by hydrogen bonds and electrostatic interactions. This first report of macrocyclic complexes of inositol hexakisphosphates provides structural insight to significant biosources of phosphorus that impact the global phosphorus cycle.",

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AU - Day, Victor W.

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PY - 2020/3/18

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N2 - Structurally elusive inositol hexakisphosphates have been trapped in host-guest sandwiches between two picolinamide macrocycles that remain intact in solution, aided by hydrogen bonds and electrostatic interactions. This first report of macrocyclic complexes of inositol hexakisphosphates provides structural insight to significant biosources of phosphorus that impact the global phosphorus cycle.

AB - Structurally elusive inositol hexakisphosphates have been trapped in host-guest sandwiches between two picolinamide macrocycles that remain intact in solution, aided by hydrogen bonds and electrostatic interactions. This first report of macrocyclic complexes of inositol hexakisphosphates provides structural insight to significant biosources of phosphorus that impact the global phosphorus cycle.

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Supramolecular traps for highly phosphorylated inositol sources of phosphorus

Abstract

Funding

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